In the title compound, trans-[PtCl2(C15H15ClFN5)2], the Pt(II) atom, located on an inversion centre, is coordinated by the purine N atoms of the 2-chloro-6-[(3-fluoro-benz-yl)amino]-9-isopropyl-9H-purine ligands and two Cl atoms in a slightly distorted trans-square-planar coordination geometry [N-Pt-Cl angles = 89.91 (5) and 90.09 (5)°]. Weak intra-molecular N-H⋯Cl contacts occur. In the crystal, C-H⋯Cl and C-H⋯F contacts, as well as weak π-π stacking inter-actions [centroid-centroid distances = 3.5000 (11) and 3.6495 (12) Å] connect the mol-ecules into a three-dimensional architecture.

Department of Inorganic Chemistry Faculty of Science Palacký University 17 listopadu 12 CZ 771 46 Olomouc Czech Republic

See more in PubMed

Agilent (2012). CrysAlis PRO Agilent Technologies Ltd, Yarnton, England.

Brandenburg, K. (2011). DIAMOND Crystal Impact GbR, Bonn, Germany.

Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. PubMed

Štarha, P., Trávníček, Z. & Popa, I. (2009). J. Inorg. Biochem. 103, 978–988. PubMed

Szüčová, L., Trávníček, Z., Popa, I. & Marek, J. (2008). Polyhedron, 27, 2710–2720.

Trávníček, Z., Marek, J. & Szüčová, L. (2006). Acta Cryst. E62, m1482–m1484.

Westrip, S. P. (2010). J. Appl. Cryst. 43, 920–925.