This paper brings a new rigorous and complete statistical approach to the data processing of the mobility curves of univalent weak acids. It is based on a fundamental equation for the mobility curve, on applying the mathematical principle of the best fit, derivation of the related nonlinear equation and finding the mathematical solution of it which gives the best estimates of the mobility curve parameters. The mathematical procedure presented here does not impose any limitations upon the numerical data used, i.e., the experimental values of mobilities and pH may be real numbers (positive, negative, zero). Further, rigorous explicit statistical formulas are derived for SDs of effective mobility, dissociation constant, and ionic mobility of fully ionized anion in question.

Institute of Analytical Chemistry Academy of Sciences of the Czech Republic Brno Czech Republic