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New Stable Cu(I) Catalyst Supported on Weakly Acidic Polyacrylate Resin for Green C-N Coupling: Synthesis of N-(Pyridin-4-yl)benzene Amines and N,N-Bis(pyridine-4-yl)benzene Amines
N. Kore, P. Pazdera,
Language English Country Switzerland
Document type Journal Article
NLK
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- MeSH
- 2-Naphthylamine chemistry MeSH
- Acrylic Resins chemistry MeSH
- Aniline Compounds chemistry MeSH
- Electrons * MeSH
- Catalysis MeSH
- Hydrogen-Ion Concentration MeSH
- Copper chemistry MeSH
- Equipment Reuse MeSH
- Piperazines chemistry MeSH
- Pyridinium Compounds chemical synthesis MeSH
- Green Chemistry Technology MeSH
- Publication type
- Journal Article MeSH
A method for preparation of a new stable Cu(I) catalyst supported on weakly acidic polyacrylate resin without additional stabilizing ligands is described. A simple and efficient methodology for Ullmann Cu(I) catalyzed C-N cross coupling reactions using this original catalyst is reported. Coupling reactions of 4-chloropyridinium chloride with anilines containing electron donating (EDG) or electron withdrawing (EWG) groups, naphthalen-2-amine and piperazine, respectively, are successfully demonstrated.
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