-
Je něco špatně v tomto záznamu ?
Occurrence of benzotriazole UV stabilizers in coastal fishes
S. Montesdeoca-Esponda, ME. Torres-Padrón, M. Novák, L. Krchová, Z. Sosa-Ferrera, JJ. Santana-Rodríguez,
Jazyk angličtina Země Velká Británie
Typ dokumentu časopisecké články
- MeSH
- chemické látky znečišťující vodu * MeSH
- ekosystém MeSH
- ryby MeSH
- tandemová hmotnostní spektrometrie * MeSH
- triazoly MeSH
- zvířata MeSH
- Check Tag
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- Geografické názvy
- Španělsko MeSH
Chemicals added in personal care products are of emerging concern because their fate and their effect on the environment is not completely known. Benzotriazole UV stabilizers (BUVSs) are compounds used in different cosmetic products, which may reach the marine environment through marine discharge from treated waters or directly from bathing areas. Once released into the aquatic ecosystem, BUVSs can be bioaccumulated by aquatic organisms. To identify the human exposure risk, it is important to have suitable analytical methods to determine the presence of BUVSs in these organisms. Because of the complexity of such a biological matrix, selective extraction and detection techniques are required to isolate and quantify these kinds of pollutants at trace levels. In the present work, we optimized a method based on microwave-assisted extraction combined with ultra-high performance liquid chromatography and mass spectrometry detection to determine six benzotriazole compounds in fish samples. The absolute extraction yields provided by the proposed method were higher than 40% for most compounds, with intra-day and inter-day relative standard deviations ranging from 0.27 to 6.06 and 1.12-21.3%, respectively. The limits of quantification were in the range of 1.13-9.66 ng g-1 (dry weight). The method was applied to the study of three species of fish (Boops boops, Sphyraena viridensis, Sphoeroides marmoratus) that were collected close to three marine outfalls of treated waters on the Gran Canaria Island (Spain) for two years. Four of the six studied compounds, UV-326, UV-328, UV-329 and UV-360, were found with concentrations ranging from 1.34 ng g-1 to 45.6 ng g-1 (dry weight).
Citace poskytuje Crossref.org
- 000
- 00000naa a2200000 a 4500
- 001
- bmc20022974
- 003
- CZ-PrNML
- 005
- 20201214125045.0
- 007
- ta
- 008
- 201125s2020 xxk f 000 0|eng||
- 009
- AR
- 024 7_
- $a 10.1016/j.jenvman.2020.110805 $2 doi
- 035 __
- $a (PubMed)32561012
- 040 __
- $a ABA008 $b cze $d ABA008 $e AACR2
- 041 0_
- $a eng
- 044 __
- $a xxk
- 100 1_
- $a Montesdeoca-Esponda, Sarah $u Instituto Universitario de Estudios Ambientales y Recursos Naturales (i-UNAT), Universidad de Las Palmas de Gran Canaria, 35017, Las Palmas de Gran Canaria, Spain.
- 245 10
- $a Occurrence of benzotriazole UV stabilizers in coastal fishes / $c S. Montesdeoca-Esponda, ME. Torres-Padrón, M. Novák, L. Krchová, Z. Sosa-Ferrera, JJ. Santana-Rodríguez,
- 520 9_
- $a Chemicals added in personal care products are of emerging concern because their fate and their effect on the environment is not completely known. Benzotriazole UV stabilizers (BUVSs) are compounds used in different cosmetic products, which may reach the marine environment through marine discharge from treated waters or directly from bathing areas. Once released into the aquatic ecosystem, BUVSs can be bioaccumulated by aquatic organisms. To identify the human exposure risk, it is important to have suitable analytical methods to determine the presence of BUVSs in these organisms. Because of the complexity of such a biological matrix, selective extraction and detection techniques are required to isolate and quantify these kinds of pollutants at trace levels. In the present work, we optimized a method based on microwave-assisted extraction combined with ultra-high performance liquid chromatography and mass spectrometry detection to determine six benzotriazole compounds in fish samples. The absolute extraction yields provided by the proposed method were higher than 40% for most compounds, with intra-day and inter-day relative standard deviations ranging from 0.27 to 6.06 and 1.12-21.3%, respectively. The limits of quantification were in the range of 1.13-9.66 ng g-1 (dry weight). The method was applied to the study of three species of fish (Boops boops, Sphyraena viridensis, Sphoeroides marmoratus) that were collected close to three marine outfalls of treated waters on the Gran Canaria Island (Spain) for two years. Four of the six studied compounds, UV-326, UV-328, UV-329 and UV-360, were found with concentrations ranging from 1.34 ng g-1 to 45.6 ng g-1 (dry weight).
- 650 _2
- $a zvířata $7 D000818
- 650 _2
- $a ekosystém $7 D017753
- 650 _2
- $a ryby $7 D005399
- 650 12
- $a tandemová hmotnostní spektrometrie $7 D053719
- 650 _2
- $a triazoly $7 D014230
- 650 12
- $a chemické látky znečišťující vodu $7 D014874
- 651 _2
- $a Španělsko $7 D013030
- 655 _2
- $a časopisecké články $7 D016428
- 700 1_
- $a Torres-Padrón, María Esther $u Instituto Universitario de Estudios Ambientales y Recursos Naturales (i-UNAT), Universidad de Las Palmas de Gran Canaria, 35017, Las Palmas de Gran Canaria, Spain.
- 700 1_
- $a Novák, Martin $u Biomedical Research Centre, University Hospital Hradec Kralove, Sokolska 581, Hradec Kralove, Czech Republic; Department of Pharmaceutical Chemistry and Pharmaceutical Analysis, Faculty of Pharmacy in Hradec Kralove, Charles University, Heyrovskeho 1203, Hradec Kralove, Czech Republic.
- 700 1_
- $a Krchová, Lucie $u Faculty of Pharmacy in Hradec Kralove, Charles University, Heyrovskeho 1203, Hradec Kralove, Czech Republic.
- 700 1_
- $a Sosa-Ferrera, Zoraida $u Instituto Universitario de Estudios Ambientales y Recursos Naturales (i-UNAT), Universidad de Las Palmas de Gran Canaria, 35017, Las Palmas de Gran Canaria, Spain.
- 700 1_
- $a Santana-Rodríguez, José Juan $u Instituto Universitario de Estudios Ambientales y Recursos Naturales (i-UNAT), Universidad de Las Palmas de Gran Canaria, 35017, Las Palmas de Gran Canaria, Spain. Electronic address: josejuan.santana@ulpgc.es.
- 773 0_
- $w MED00002657 $t Journal of environmental management $x 1095-8630 $g Roč. 269, č. - (2020), s. 110805
- 856 41
- $u https://pubmed.ncbi.nlm.nih.gov/32561012 $y Pubmed
- 910 __
- $a ABA008 $b sig $c sign $y a $z 0
- 990 __
- $a 20201125 $b ABA008
- 991 __
- $a 20201214125045 $b ABA008
- 999 __
- $a ok $b bmc $g 1595293 $s 1113650
- BAS __
- $a 3
- BAS __
- $a PreBMC
- BMC __
- $a 2020 $b 269 $c - $d 110805 $e 20200526 $i 1095-8630 $m Journal of environmental management $n J Environ Manage $x MED00002657
- LZP __
- $a Pubmed-20201125
