Modification of ultrahigh-molecular-weight polyethylene (UHMWPE) consisting of a combination of gamma irradiation and subsequent thermal treatment has been performed in order to investigate the resultant changes to its supramolecular structure. In the first step the polymer was irradiated by gamma rays at laboratory temperature under nitrogen. Five radiation doses (25, 50, 100, 150, and 200 kGy) were applied at two dose rates (0.25 and 2.5 kGy/h). In the second step the irradiated samples were thermally treated above the UHMWPE melting temperature. Insoluble fraction, crystallinity (fraction), and lamellar periodicity were determined as functions of dose and dose rate for irradiated samples before and after thermal treatment. Both modification steps were shown to produce substantial changes in the UHMWPE structure.

Institute of Macromolecular Chemistry Academy of Sciences of the Czech Republic Heyrovsky Square 2 162 06 Prague 6 Czech Republic

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