Simple, straightforward and optimized procedures for preparing extended pi-conjugated linkers are described. Either unsubstituted or 4-donor substituted pi-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl pi-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki-Miyaura or Sonogashira coupling reactions.

Institute of Organic Chemistry and Technology Faculty of Chemical Technology University of Pardubice nám Cs legií 565 Pardubice 532 10 Czech Republic

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Imidazole as a parent π-conjugated backbone in charge-transfer chromophores