Fluorescence anisotropy measurements were performed on a set of multichromophoric compounds, which contain a different number of aminopyrenyl moieties linked to a triazine ring, in order to reveal the nature of both the electronic excited states and relaxation pathways of the compounds. Our experimental results complement quantum chemical calculations. We propose that the lowest excited state from which fluorescence proceeds is localized on a single individual aminopyrene moiety. In contrast, excitation to a higher excited state is likely followed by a migration of energy to another nearby aminopyrene chromophore before the internal conversion to the emitting state takes place. We suggest that this migration is responsible for the experimentally measured decrease of fluorescence anisotropy of the studied compounds.

Department of Physical Electronics Faculty of Nuclear Sciences and Physical Engineering Czech Technical University Prague 5 Holešovičkách 2 180 00 Praha 8 Czech Republic

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Phys Rev Lett. 2005 Oct 21;95(17):177402 PubMed

J Phys Chem B. 2007 Aug 16;111(32):9468-83 PubMed