Orthogonal photocleavage of a monochromophoric linker
Language English Country United States Media print
Document type Journal Article, Research Support, Non-U.S. Gov't
PubMed
20684513
DOI
10.1021/ja1047736
Knihovny.cz E-resources
- MeSH
- Photochemistry MeSH
- Molecular Structure MeSH
- Nitrobenzenes chemical synthesis chemistry MeSH
- Stereoisomerism MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Names of Substances
- Nitrobenzenes MeSH
The 4-acetyl-2-nitrobenzyl moiety, substituted in both benzylic and phenacyl positions with leaving groups, has been proposed as a monochromophoric photocleavable linker. The attached groups can be disconnected selectively and orthogonally upon irradiation.
References provided by Crossref.org
Visible-to-NIR-Light Activated Release: From Small Molecules to Nanomaterials
Photoremovable protecting groups in chemistry and biology: reaction mechanisms and efficacy
