Continuous Production of Pure Titanium with Ultrafine to Nanocrystalline Microstructure

. 2020 Jan 11 ; 13 (2) : . [epub] 20200111

Status PubMed-not-MEDLINE Jazyk angličtina Země Švýcarsko Médium electronic

Typ dokumentu časopisecké články

Perzistentní odkaz   https://www.medvik.cz/link/pmid31940761

This work deals with the application of the Conform SPD (Severe Plastic Deformation) continuous extrusion process for ultrafine to nanostructured pure titanium production. The process has been derived from the Equal Channel Angular Pressing (ECAP) technique but, unlike ECAP, it offers continuous production of high-strength wire. This study describes the Conform SPD process combined with subsequent cold working (rotary swaging technique), its potential for commercial application, and the properties of high-strength wires of pure titanium. High-strength wire of titanium Grade 4 is the product. Titanium Grade 4 reaches ultimate strengths up to 1320 MPa. This value is more than twice the ultimate strength of the unprocessed material. The typical grain size upon processing ranges from 200 to 500 nm. Process development supported by FEM analysis together with detailed microstructure characterization accompanied by mechanical properties investigation is presented.

Zobrazit více v PubMed

Sabirov I., Enikeev N.A., Murashkin M.Y., Valiev R.Z. Bulk Nanostructured Materials with Multifunctional Properties. Springer; Berlin, Germany: 2015.

Mishnaevsky L., Levashov E., Valiev R.Z., Segurado J., Sabirov I., Enikeev N., Prokoshkin S., Solov’Yov A.V., Korotitskiy A., Gutmanas E., et al. Nanostructured titanium-based materials for medical implants: Modeling and development. Mater. Sci. Eng. R Rep. 2014;81:1–19. doi: 10.1016/j.mser.2014.04.002. DOI

Mishra A., Kad B.K., Gregori F., Meyers M.A. Microstructural evolution in copper subjected to severe plastic deformation: Experiments and analysis. Acta Mater. 2007;55:13–28. doi: 10.1016/j.actamat.2006.07.008. DOI

Gomes C.C., Moreira L.M., Santos V.J.S.V., Ramos A.S., Lyon J.P., Soares C.P., Santos F.V. Assessment of the genetic risks of a metallic alloy used in medical implants. Genet. Mol. Biol. 2011;34:116–121. doi: 10.1590/S1415-47572010005000118. PubMed DOI PMC

Okazaki Y., Gotoh E., Manabe T., Kobayashi K. Comparison of metal concentrations in rat tibia tissues with various metallic implants. Biomaterials. 2004;25:5913–5920. doi: 10.1016/j.biomaterials.2004.01.064. PubMed DOI

Lin C.W., Ju C.P., Chern Lin J.H. A comparison of the fatigue behavior of cast Ti-7.5Mo with c.p. titanium, Ti-6Al-4V and Ti-13Nb-13Zr alloys. Biomaterials. 2005;26:2899–2907. doi: 10.1016/j.biomaterials.2004.09.007. PubMed DOI

Zreiqat H., Valenzuela S.M., Ben Nissan B., Roest R., Knabe C., Radlanski R.J., Renz H., Evans P.J. The effect of surface chemistry modification of titanium alloy on signalling pathways in human osteoblasts. Biomaterials. 2005;26:7579–7586. doi: 10.1016/j.biomaterials.2005.05.024. PubMed DOI

Raab G.I., Valiev R., Gunderov D., Lowe T.C., Misra A., Zhu Y.T. Long-Length Ultrafine-Grained Titanium Rods Produced by ECAP-Conform. Mater. Sci. Forum. 2009;584–586:80–85. doi: 10.4028/www.scientific.net/MSF.584-586.80. DOI

Zemko M., Kubina T., Dlouhý J., Kover M., Hodek J. Technological aspects of preparation of nanostructured titanium wire using a CONFORM machine. IOP Conf. Ser. Mater. Sci. Eng. 2014;63:012049. doi: 10.1088/1757-899X/63/1/012049. DOI

Palán J., Maleček L., Hodek J., Zemko M., Dzugan J. Possibilities of biocompatible material production using conform SPD technology. Arch. Mater. Sci. Eng. 2017;88:5–11. doi: 10.5604/01.3001.0010.7746. DOI

Kubina T., Dlouhý J., Kövér M., Hodek J. Study of Thermal Stability of Ultra Fine-Grained Commercially Pure Titanium Wire Prepared in Conform Equipment. Mater. Sci. Forum. 2014;782:415–420. doi: 10.4028/www.scientific.net/MSF.782.415. DOI

Li B., Li C.H., Yao X.J., Song B.Y. Effects of Continuous Extrusion on Microstructure Evolution and Property Characteristics of Brass Alloy. Adv. Mater. Res. 2011;189–193:2921–2924. doi: 10.4028/www.scientific.net/AMR.189-193.2921. DOI

He Y.L., Gao F., Song B.Y., Fu R., Wu G.M., Li J., Jiang L. Grain Refinement of Magnesium Alloys by CONFORM: A Continuous Severe Plastic Deformation Route? Mater. Sci. Forum. 2012;706–709:1781–1786. doi: 10.4028/www.scientific.net/MSF.706-709.1781. DOI

Etherington C. Conform—A New Concept for the Continuous Extrusion Forming of Metals. J. Manuf. Sci. Eng. Trans. ASME. 1973;96:893–900. doi: 10.1115/1.3438458. DOI

Palán J., Procházka R., Džugan J., Nacházel J., Duchek M., Gergely N., Minárik P., Horvát K. Comprehensive Evaluation of the Properties of Ultrafine to Nanocrystalline Grade 2 Titanium Wires. Materials. 2018;11:2522. doi: 10.3390/ma11122522. PubMed DOI PMC

Valiev R.Z., Langdon T.G. Principles of equal-channel angular pressing as a processing tool for grain refinement. Prog. Mater. Sci. 2006;51:881–981. doi: 10.1016/j.pmatsci.2006.02.003. DOI

Xu C., Schroeder S., Berbon P.B., Langdon T.G. Principles of ECAP-Conform as a continuous process for achieving grain refinement: Application to an aluminum alloy. Acta Mater. 2010;58:1379–1386. doi: 10.1016/j.actamat.2009.10.044. DOI

Zhao X., Yang X., Liu X., Wang X., Langdon T.G. The processing of pure titanium through multiple passes of ECAP at room temperature. Mater. Sci. Eng. A. 2010;527:6335–6339. doi: 10.1016/j.msea.2010.06.049. DOI

Krystian M., Huber D., Horky J. Equal channel angular pressing (ECAP) and forging of commercially pure titanium (CP-Ti) AIP Conf. Proc. 2017;1896

Semenova I.P., Valiev R.Z., Yakushina E.B., Salimgareeva G.H., Lowe T.C. Strength and fatigue properties enhancement in ultrafine-grained Ti produced by severe plastic deformation. J. Mater. Sci. 2008;43:7354–7359. doi: 10.1007/s10853-008-2984-4. PubMed DOI PMC

Semenova I.P., Polyakov A.V., Raab G.I., Lowe T.C., Valiev R.Z. Enhanced fatigue properties of ultrafine-grained Ti rods processed by ECAP-Conform. J. Mater. Sci. 2012;47:7777–7781. doi: 10.1007/s10853-012-6675-9. DOI

Wu H., Jiang J., Liu H., Sun J., Gu Y., Tang R., Zhao X., Ma A. Fabrication of an Ultra-Fine Grained Pure Titanium with High Strength and Good Ductility via ECAP plus Cold Rolling. Metals (Basel) 2017;7:563. doi: 10.3390/met7120563. DOI

Gunderov D.V., Polyakov A.V., Semenova I.P., Raab G.I., Churakova A.A., Gimaltdinova E.I., Sabirov I., Segurado J., Sitdikov V.D., Alexandrov I.V., et al. Evolution of microstructure, macrotexture and mechanical properties of commercially pure Ti during ECAP-conform processing and drawing. Mater. Sci. Eng. A. 2013;562:128–136. doi: 10.1016/j.msea.2012.11.007. DOI

Hodek J., Zemko M. FEM model of continuous extrusion of titanium in deform software. Tanger Ltd. Plzeň Czech Repub. 2013:347–351.

Hatherly F.J.H., Hatherly M. Recrystallization and Related Annealing Phenomena. 2nd ed. Pergamon; Bergama, Turkey: 2004.

Nourbakhsh S., O’Brien T.D. Texture formation and transition in Cold-rolled titanium. Mater. Sci. Eng. 1988;100:109–114. doi: 10.1016/0025-5416(88)90245-5. DOI

Thomas B.M., Derguti F., Jackson M. Continuous extrusion of a commercially pure titanium powder via the Conform process. Mater. Sci. Technol. (UK) 2017;33:899–903. doi: 10.1080/02670836.2016.1245256. DOI

Thomas B.M. Continuous Extrusion of Commercially Pure Titanium Powder. University of Sheffield; Sheffield, UK: 2015.

Valiev R.Z., Alexandrov I.V. Nanostructured materials from severe plastic deformation. Prog. Mater. Sci. 2000;45:103–189. doi: 10.1016/S0079-6425(99)00007-9. DOI

Jansson B., Rolfson M., Thuvander A., Melander A., Wullimann C. Calculation of microstructure and hardness of hot rolled steel bars. Mater. Sci. Technol. 2014;7:118–128. doi: 10.1179/mst.1991.7.2.118. DOI

Eivani A.R., Zhou J., Duszczyk J. Mechanism of the formation of peripheral coarse grain structure in hot extrusion of Al-4.5Zn-1Mg. Philos. Mag. 2016;96:1188–1196. doi: 10.1080/14786435.2016.1157637. DOI

Kubina T., Dlouhý J., Köver M., Dománková M., Hodek J. Preparation and thermal stability of ultra-fine and nano-grained commercially pure titanium wires using conform equipment. Mater. Tehnol. 2015;49:213–217. doi: 10.17222/mit.2013.226. DOI

Palán J., Procházka R., Zemko M. The microstructure and mechanical properties evaluation of UFG Titanium Grade 4 in relation to the technological aspects of the CONFORM SPD process. Procedia Eng. 2017;207:1439–1444. doi: 10.1016/j.proeng.2017.10.910. DOI

Najít záznam

Citační ukazatele

Nahrávání dat ...

Možnosti archivace

Nahrávání dat ...