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Covalent Cross-Linking of 2H-MoS2 Nanosheets

. 2021 Feb 10 ; 27 (9) : 2993-2996. [epub] 20210112

Status PubMed-not-MEDLINE Language English Country Germany Media print-electronic

Document type Journal Article

Grant support
CTQ2017-86060-P Ministerio de Economía, Industria y Competitividad, Gobierno de España
CTQ2016-79419-R Ministerio de Economía, Industria y Competitividad, Gobierno de España
SEV- 2016-0686 Ministerio de Economía, Industria y Competitividad, Gobierno de España
MAD2D-CM S2013/ MIT-3007 Comunidad de Madrid
LM2018110 Ministerstvo Školství, Mládeže a Tělovýchovy
ERC-StG-307609 European Research Council - International
ERC-AdG-742684 European Research Council - International
ERC-PoC-842606 European Research Council - International

The combination of 2D materials opens a wide range of possibilities to create new-generation structures with multiple applications. Covalently cross-linked approaches are a ground-breaking strategy for the formation of homo or heterostructures made by design. However, the covalent assembly of transition metal dichalcogenides flakes is relatively underexplored. Here, a simple covalent cross-linking method to build 2H-MoS2 -MoS2 homostructures is described, using commercially available bismaleimides. These assemblies are mainly connected vertically, basal plane to basal plane, creating specific molecular sized spaces between MoS2 sheets. Therefore, this straightforward approach gives access to the controlled connection of sulfide-based 2D materials.

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. 2022 Jun ; 14 (6) : 695-700. [epub] 20220425

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