Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol
Status PubMed-not-MEDLINE Jazyk angličtina Země Anglie, Velká Británie Médium print-electronic
Typ dokumentu časopisecké články
PubMed
33688895
DOI
10.1039/d1cc00909e
Knihovny.cz E-zdroje
- Publikační typ
- časopisecké články MeSH
Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved dioxygen directly oxidized methane to methanol, which can be released without the aid of an effluent to the gas phase at RT.
Citace poskytuje Crossref.org
Organization of Cooperating Aluminum Pairs in Ferrierite Evidenced by Luminescence Quenching
