Photocatalytic H2 Generation: Controlled and Optimized Dispersion of Single Atom Co-Catalysts Based on Pt-TCPP Planar Adsorption on TiO2
Status PubMed-not-MEDLINE Language English Country Germany Media print-electronic
Document type Journal Article
Grant support
CZ.02.1.01/0.0/0.0/15_003/0000416
European Regional Development Fund
23-08019X
EXPRO grant
DE 1830/ 5-1 | SCHM 1597/35-1
Emerging Talents Initiatives
Deutsche Forschungsgemeinschaft
- Keywords
- hydrogen evolution, photocatalysis, platinum, porphyrins, single-atom catalysts,
- Publication type
- Journal Article MeSH
When using single atoms (SAs) as a co-catalyst in photocatalytic H2 generation, achieving a well-dispersed, evenly distributed and adjustable SA surface density on a semiconductor surface is a challenging task. In the present work we use the planar adsorption of tetrakis-(4-carboxyphenyl)-porphyrin (TCPP) and its platinum coordinated analogue, Pt-TCPP, onto anatase TiO2 surfaces to establish a spatially controlled decoration of SAs. We show that the surface Pt SA density can be very well controlled by co-adsorption of Pt-TCPP and TCPP in the planar monolayer regime, and by adjusting the Pt-TCPP to TCPP ratio a desired well dispersed surface density of SAs up to 2.6×105 atoms μm-2 can be established (which is the most effective Pt SA loading for photocatalysis). This distribution and the SA state are maintained after a thermal treatment in air, and an optimized SA density as well as a most active form of Pt for photocatalytic H2 evolution can be established and maintained.
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C. Gao, J. Low, R. Long, T. Kong, J. Zhu, Y. Xiong, Chem. Rev. 2020, 120, 12175-12216.
Z.-H. Xue, D. Luan, H. Zhang, X. W. Lou, Joule 2022, 6, 92-133.
Q. Wang, D. Zhang, Y. Chen, W.-F. Fu, X.-J. Lv, ACS Sustainable Chem. Eng. 2019, 7, 6430-6443.
A. Wang, J. Li, T. Zhang, Nat. Chem. Rev. 2018, 2, 65-81.
S. J. Tauster, S. C. Fung, R. L. Garten, J. Am. Chem. Soc. 1978, 100, 170-175.
S. J. Tauster, Acc. Chem. Res. 1987, 20, 389-394.
T. W. van Deelen, C. Hernández Mejía, K. P. de Jong, Nat. Catal. 2019, 2, 955-970.
S. Qin, J. Will, H. Kim, N. Denisov, S. Carl, E. Spiecker, P. Schmuki, ACS Energy Lett. 2023, 8, 1209-1214.
U. Heiz, A. Sanchez, S. Abbet, W. D. Schneider, J. Am. Chem. Soc. 1999, 121, 3214-3217.
S. Hejazi, S. Mohajernia, B. Osuagwu, G. Zoppellaro, P. Andryskova, O. Tomanec, S. Kment, R. Zbořil, P. Schmuki, Adv. Mater. 2020, 32, 1908505.
Y. Zhang, J. Zhao, H. Wang, B. Xiao, W. Zhang, X. Zhao, T. Lv, M. Thangamuthu, J. Zhang, Y. Guo, J. Ma, L. Lin, J. Tang, R. Huang, Q. Liu, Nat. Commun. 2022, 13, 58.
T. Wang, X. Tao, X. Li, K. Zhang, S. Liu, B. Li, Small 2021, 17, 2006255.
C. Ji, W. Wang, E.-S. M. El-Sayed, G. Liu, Y. Si, K. Su, Z. Ju, F. Wu, D. Yuan, Appl. Catal. B 2021, 285, 119782.
Y. Wang, S. Qin, N. Denisov, H. Kim, E. Spiecker, P. Schmuki, Adv. Mater. 2023, 35, 2211814.
X. Chen, S. Qin, N. Denisov, S.-Z. Kure-Chu, P. Schmuki, Electrochim. Acta 2023, 446, 142081.
S. Qin, N. Denisov, J. Will, J. Kolařík, E. Spiecker, P. Schmuki, Solar RRL 2022, 6, 2101026.
Z. Wu, I. Hwang, G. Cha, S. Qin, O. Tomanec, Z. Badura, S. Kment, R. Zboril, P. Schmuki, Small 2021, 2104892.
S. Qin, N. Denisov, B. B. Sarma, I. Hwang, D. E. Doronkin, O. Tomanec, S. Kment, P. Schmuki, Adv. Mater. Interfaces 2022, 9, 2200808.
L. DeRita, J. Resasco, S. Dai, A. Boubnov, H. V. Thang, A. S. Hoffman, I. Ro, G. W. Graham, S. R. Bare, G. Pacchioni, X. Pan, P. Christopher, Nat. Mater. 2019, 18, 746-751.
L. Chen, R. R. Unocic, A. S. Hoffman, J. Hong, A. H. Braga, Z. Bao, S. R. Bare, J. Szanyi, JACS Au 2021, 1, 977-986.
L. DeRita, S. Dai, K. Lopez-Zepeda, N. Pham, G. W. Graham, X. Pan, P. Christopher, J. Am. Chem. Soc. 2017, 139, 14150-14165.
N. Denisov, S. Qin, J. Will, B. N. Vasiljevic, N. V. Skorodumova, I. A. Pašti, B. B. Sarma, B. Osuagwu, T. Yokosawa, J. Voss, J. Wirth, E. Spiecker, P. Schmuki, Adv. Mater. 2022, 35, 2206569.
W. Auwärter, D. Écija, F. Klappenberger, J. V. Barth, Nat. Chem. 2015, 7, 105-120.
Z. Zhang, S. Hou, Z. Zhu, Z. Liu, Langmuir 2000, 16, 537-540.
K. W. Hipps, U. Mazur, Langmuir 2018, 34, 3-17.
M. G. Walter, A. B. Rudine, C. C. Wamser, J. Porphyrins Phthalocyanines 2010, 14, 759-792.
W. M. Campbell, K. W. Jolley, P. Wagner, K. Wagner, P. J. Walsh, K. C. Gordon, L. Schmidt-Mende, M. K. Nazeeruddin, Q. Wang, M. Grätzel, D. L. Officer, J. Phys. Chem. C 2007, 111, 11760-11762.
H. Yu, X. Wu, Q. Mu, Z. Wei, Y. Gu, X. Yuan, Y. Lu, Z. Deng, Y. Peng, Chin. Chem. Lett. 2021, 32, 3833-3836.
J. Dong, Q. Mo, Y. Wang, L. Jiang, L. Zhang, C.-Y. Su, Chem. Eur. J. 2022, 28, e202200555.
X. He, Q. He, Y. Deng, M. Peng, H. Chen, Y. Zhang, S. Yao, M. Zhang, D. Xiao, D. Ma, B. Ge, H. Ji, Nat. Commun. 2019, 10, 3663.
Q. Li, G. Mathur, S. Gowda, S. Surthi, Q. Zhao, L. Yu, J. S. Lindsey, D. F. Bocian, V. Misra, Adv. Mater. 2004, 16, 133-137.
S. Cherian, C. C. Wamser, J. Phys. Chem. B 2000, 104, 3624-3629.
M. Y. Choi, J. A. Pollard, M. A. Webb, J. L. McHale, J. Am. Chem. Soc. 2003, 125, 810-820.
Q. Zuo, T. Liu, C. Chen, Y. Ji, X. Gong, Y. Mai, Y. Zhou, Angew. Chem. Int. Ed. 2019, 58, 10198-10203.
Y.-L. Liu, X.-Y. Liu, L. Feng, L.-X. Shao, S.-J. Li, J. Tang, H. Cheng, Z. Chen, R. Huang, H.-C. Xu, J.-L. Zhuang, ChemSusChem 2022, 15, e202102603.
D. Li, H.-Q. Xu, L. Jiao, H.-L. Jiang, EnergyChem 2019, 1, 100005.
H. Kim, N. Kim, J. Ryu, Inorg. Chem. Front. 2021, 8, 4107-4148.
A. Fujishima, X. Zhang, D. A. Tryk, Surf. Sci. Rep. 2008, 63, 515-582.
S. Chen, T. Takata, K. Domen, Nat. Rev. Mater. 2017, 2, 17050.
J. Yu, L. Qi, M. Jaroniec, J. Phys. Chem. C 2010, 114, 13118-13125.
S. Qin, J. Guo, X. Chen, R. Cao, N. Denisov, Y.-Y. Song, P. Schmuki, J. Mater. Chem. A 2023, 11, 17759-17768.
G. Cha, A. Mazare, I. Hwang, N. Denisov, J. Will, T. Yokosawa, Z. Badura, G. Zoppellaro, A. B. Tesler, E. Spiecker, P. Schmuki, Electrochim. Acta 2022, 412, 140129.
H. Kim, Y. Wang, N. Denisov, Z. Wu, Š. Kment, P. Schmuki, J. Mater. Sci. 2022, 57, 12960-12970.
S.-Y. Lu, M. Jin, Y. Zhang, Y.-B. Niu, J.-C. Gao, C. M. Li, Adv. Energy Mater. 2018, 8, 1702545.
J. Balajka, M. A. Hines, W. J. I. DeBenedetti, M. Komora, J. Pavelec, M. Schmid, U. Diebold, Science 2018, 361, 786-789.
A. G. Thomas, K. L. Syres, Chem. Soc. Rev. 2012, 41, 4207-4217.
K. C. Smith, D. A. Saenz, D. Zemlyanov, A. A. Voevodin (2014), “XPS Thickness Solver,” https://nanohub.org/resources/xpsts. (DOI: 10.4231/D3FJ29D7X).
D. Y. Zemlyanov, M. Jespersen, D. N. Zakharov, J. Hu, R. Paul, A. Kumar, S. Pacley, N. Glavin, D. Saenz, K. C. Smith, T. S. Fisher, A. A. Voevodin, Nanotechnology 2018, 29, 115705.
NIST Standard Reference Database 71 https://doi.org/10.18434/T48C78.
C. Maddi, F. Bourquard, V. Barnier, J. Avila, M.-C. Asensio, T. Tite, C. Donnet, F. Garrelie, Sci. Rep. 2018, 8, 3247.
