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Mechanochromic luminescence in copper nanoclusters: resolving structural transitions through microcrystal electron diffraction

Nagar, Harshita
Autor Nagar, Harshita ORCID DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology, Madras, Chennai - 600036, India. pradeep@iitm.ac.in International Centre for Clean Water, Chennai-600113, India
Duary, Subrata
Autor Duary, Subrata DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology, Madras, Chennai - 600036, India. pradeep@iitm.ac.in International Centre for Clean Water, Chennai-600113, India
Yadav, Vivek
Autor Yadav, Vivek DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology, Madras, Chennai - 600036, India. pradeep@iitm.ac.in International Centre for Clean Water, Chennai-600113, India
Kini, Amoghavarsha Ramachandra
Autor Kini, Amoghavarsha Ramachandra DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology, Madras, Chennai - 600036, India. pradeep@iitm.ac.in International Centre for Clean Water, Chennai-600113, India
Antharjanam, Sudhadevi
Autor Antharjanam, Sudhadevi Sophisticated Analytical Instruments Facility (SAIF), Indian Institute of Technology, Madras, Chennai - 600036, India
Base, Tomas
Autor Base, Tomas ORCID Department of Synthesis, Institute of Inorganic Chemistry, The Czech Academy of Science, 1001 Husinec-Rez, 25068, Czech Republic. tbase@iic.acs.cz
Som, Anirban
Autor Som, Anirban ORCID DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology, Madras, Chennai - 600036, India. pradeep@iitm.ac.in International Centre for Clean Water, Chennai-600113, India
Nannenga, Brent L
Autor Nannenga, Brent L ORCID School of Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona, USA. brent.nannenga@asu.edu
Pradeep, Thalappil
Autor Pradeep, Thalappil ORCID DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology, Madras, Chennai - 600036, India. pradeep@iitm.ac.in International Centre for Clean Water, Chennai-600113, India

Chemical communications (Cambridge, England). 2025 Jul 15 ; 61 (58) : 10764-10767. [epub] 20250715

Chem Commun (Camb)
ISSN 1364-548X | 1359-7345
Zdroj

Status PubMed-not-MEDLINE Jazyk angličtina Země Anglie, Velká Británie Médium electronic

Typ dokumentu časopisecké články

Perzistentní odkaz https://www.medvik.cz/link/pmid40546081

PubMed 40546081
DOI 10.1039/d5cc02594j
Knihovny.cz E-zdroje

Publikační typ
časopisecké články MeSH

MicroED reveals insights into mechanochromic luminescence in copper nanoclusters, demonstrating structural transitions from crystalline to amorphous state upon grinding, with restoration of crystallinity following solvent exposure. Luminescence switching occurs due to reversible amorphization-recrystallization rather than chemical changes, providing critical design principles for such stimuli-responsive materials.

Department of Synthesis Institute of Inorganic Chemistry The Czech Academy of Science 1001 Husinec Rez 25068 Czech Republic

DST Unit of Nanoscience Department of Chemistry Indian Institute of Technology Madras Chennai 600036 India

International Centre for Clean Water Chennai 600113 India

School of Engineering of Matter Transport and Energy Arizona State University Tempe Arizona USA

Sophisticated Analytical Instruments Facility Indian Institute of Technology Madras Chennai 600036 India

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Mechanochromic luminescence in copper nanoclusters: resolving structural transitions through microcrystal electron diffraction

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