Detail
Článek
Článek online
FT
Medvik - BMČ
  • Je něco špatně v tomto záznamu ?

Automatická spektrálna dekonvolúcia na analýzu rezíduí pesticídov metódou rýchlej GC-MS
[Automated mass spectral deconvolution for pesticide residues analysis by fast GC-MS]

Michal Kirchner, Silvia Ondreková, Eva Matisová

. 2007 ; 101 (3) : 220-224.

Jazyk slovenština Země Česko

Perzistentní odkaz   https://www.medvik.cz/link/bmc07501391

The aim of this study was to estimate the lowest concentration of pesticide residues in non-fatty food matrix at which the residues can be successfully identified by automatic spectral deconvolution software AMDIS. For GC-MS measurements fast GC with narrow capillary column was utilized. For a mixture of 18 pesticides, the identification was successful at concentration levels 4–0.4 mg kg-1 in real matrix samples (apples). With decreasing concentration, the number of identified pesticides and the quality of deconvoluted spectra decreased. The calculated limits of full-scan detection ranged from 0.20 ng for chlorpyrifos to 1.10 ng for captan. Software AMDIS with the used experimental set-up is not sufficiently sensitive for reliable identification of pesticide residues in non-fatty food matrices with low maximal residual limits (e.g. baby food 0.01 mg kg-1).

Automated mass spectral deconvolution for pesticide residues analysis by fast GC-MS

Grant č. APVV-20-000705

Bibliografie atd.

Lit.: 7

000      
02628naa 2200397 a 4500
001      
bmc07501391
003      
CZ-PrNML
005      
20111210121133.0
008      
071126s2007 xr e slo||
009      
AR
040    __
$a ABA008 $b cze $c ABA008 $d ABA008 $e AACR2
041    0_
$a slo $b eng
044    __
$a xr
100    1_
$a Kirchner, Michal $7 xx0062706
245    10
$a Automatická spektrálna dekonvolúcia na analýzu rezíduí pesticídov metódou rýchlej GC-MS / $c Michal Kirchner, Silvia Ondreková, Eva Matisová
246    11
$a Automated mass spectral deconvolution for pesticide residues analysis by fast GC-MS
314    __
$a Ústav analytickej chémie, Fakulta chemickej a potravinárskej technológie, Slovenská technická univerzita, Bratislava
500    __
$a Grant č. APVV-20-000705
504    __
$a Lit.: 7
520    9_
$a The aim of this study was to estimate the lowest concentration of pesticide residues in non-fatty food matrix at which the residues can be successfully identified by automatic spectral deconvolution software AMDIS. For GC-MS measurements fast GC with narrow capillary column was utilized. For a mixture of 18 pesticides, the identification was successful at concentration levels 4–0.4 mg kg-1 in real matrix samples (apples). With decreasing concentration, the number of identified pesticides and the quality of deconvoluted spectra decreased. The calculated limits of full-scan detection ranged from 0.20 ng for chlorpyrifos to 1.10 ng for captan. Software AMDIS with the used experimental set-up is not sufficiently sensitive for reliable identification of pesticide residues in non-fatty food matrices with low maximal residual limits (e.g. baby food 0.01 mg kg-1).
650    _2
$a rezidua pesticidů $x analýza $7 D010573
650    _2
$a chemické techniky analytické $x metody $7 D002623
650    _2
$a software $7 D012984
650    _2
$a chromatografie plynová $x metody $7 D002849
650    _2
$a financování vládou $7 D005380
700    1_
$a Ondreková, Silvia. $7 _BN001655
700    1_
$a Matisová, Eva, $d 1942- $7 mzk2004236841
773    0_
$w MED00011010 $t Chemické listy $g Roč. 101, č. 3 (2007), s. 220-224 $x 0009-2770
856    41
$u http://www.chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/1811/1811 $y plný text volně přístupný
910    __
$a ABA008 $b B 1918 $c 395 $y 1
990    __
$a 20071126142111 $b ABA008
991    __
$a 20071128093946 $b ABA008
999    __
$a ok $b bmc $g 617001 $s 469433
BAS    __
$a 3
BMC    __
$a 2007 $b 101 $c 3 $d 220-224 $i 0009-2770 $m Chemické listy $x MED00011010
LZP    __
$a 2007-14/mkmv

Najít záznam

Citační ukazatele

Možnosti archivace