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Polarographic behavior and determination of 1,1-Dimethyl-3-phenyltriazene
Ljubiša M. Ignjatović, Jiří Barek, Jiří Zima, Dragan A. Marković
Language English Country Czech Republic
NLK
ProQuest Central
from 2005-01-01 to 2011
- MeSH
- Research Support as Topic MeSH
- Carcinogens analysis MeSH
- Polarography methods MeSH
- Triazenes analysis MeSH
Polarographic behavior of the genotoxic substance 1,1-dimethyl-3-phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.
Grant č. LC 06035 Ministerstvo školství, kultury a sportu -- Grant č. MSM 0021620857 Ministerstvo školství, kultury a sportu -- Grant č. 142047 Ministerstvo životního prostředí Srbska
Bibliography, etc.Lit.: 23
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- $a Faculty of Physical Chemistry, University of Belgrade, Belgrade
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- $a Lit.: 23
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- $a Polarographic behavior of the genotoxic substance 1,1-dimethyl-3-phenyltriazene was investigated and optimum conditions were found for its determination by sampled direct current polarography and differential pulse polarography at a static mercury drop electrode in the concentration range from 1 × 10-4 to 1 × 10-7 mol l-1. It was established that for reduction of the triazene group four electrons are required resulting in the formation of amino and hydrazo compound. The resulting products were identified, and the reduction pathway was proposed.
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