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Controlled/living surface-initiated ATRP of antifouling polymer brushes from gold in PBS and blood sera as a model study for polymer modifications in complex biological media
C. Rodriguez-Emmenegger, E. Hasan, O. Pop-Georgievski, M. Houska, E. Brynda, AB. Alles,
Language English Country Germany
Document type Journal Article, Research Support, Non-U.S. Gov't
NLK
Medline Complete (EBSCOhost)
from 2012-06-01 to 1 year ago
Wiley Online Library (archiv)
from 2001-01-01 to 2012-12-31
- MeSH
- Adsorption MeSH
- Acrylamides chemistry MeSH
- Biocompatible Materials chemical synthesis MeSH
- Blood Proteins chemistry MeSH
- Methacrylates chemistry MeSH
- Polyethylene Glycols chemistry MeSH
- Polymerization MeSH
- Buffers MeSH
- Serum MeSH
- Cattle MeSH
- Spectroscopy, Fourier Transform Infrared MeSH
- Materials Testing MeSH
- Water MeSH
- Gold chemistry MeSH
- Animals MeSH
- Check Tag
- Cattle MeSH
- Animals MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
The use of PBS, 10% FBS or 10% CS as media for SI-ATRP is reported. Controlled/living SI-ATRP of MeOEGMA in PBS is achieved leading to better control than in water. The livingness is confirmed by chain extension with MeOEGMA or carboxybetaine acrylamide. This technique is successfully adopted for the polymerization of MeOEGMA in 10% FBS or CS as models for complex biological media with reasonable control of the brush growth. All prepared brushes show excellent antifouling properties.
College of Engineering Universidad de la Republica Montevideo 11300 Uruguay
Department of Chemistry University of Liverpool L69 3BX United Kingdom
Institute of Macromolecular Chemistry AS CR Heyrovskeho Sq 2 Prague 6 16206 Czech Republic
References provided by Crossref.org
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- $a The use of PBS, 10% FBS or 10% CS as media for SI-ATRP is reported. Controlled/living SI-ATRP of MeOEGMA in PBS is achieved leading to better control than in water. The livingness is confirmed by chain extension with MeOEGMA or carboxybetaine acrylamide. This technique is successfully adopted for the polymerization of MeOEGMA in 10% FBS or CS as models for complex biological media with reasonable control of the brush growth. All prepared brushes show excellent antifouling properties.
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