-
Je něco špatně v tomto záznamu ?
Model for photodegradation of polybrominated diphenyl ethers
M. Vesely, Z. Vajglova, P. Kotas, J. Kristal, R. Ponec, V. Jiricny,
Jazyk angličtina Země Německo
Typ dokumentu časopisecké články, práce podpořená grantem
NLK
ProQuest Central
od 1997-03-01 do Před 1 rokem
Health & Medicine (ProQuest)
od 1997-03-01 do Před 1 rokem
Public Health Database (ProQuest)
od 1997-03-01 do Před 1 rokem
- MeSH
- fotolýza * MeSH
- halogenované difenylethery chemie MeSH
- molekulární struktura MeSH
- počítačová simulace MeSH
- reprodukovatelnost výsledků MeSH
- retardanty hoření analýza MeSH
- teoretické modely * MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
Polybrominated diphenyl ethers (PBDE) were, and in some countries still are, used as flame retardants for plastic materials. When released from plastics, PDBE cause harm to the environment. This creates the incentive for further investigation of the PBDE degradation. This work focused on a formulation of a PBDE photodegradation model based on the PBDE properties obtained by the quantum chemical calculations. The proposed model predicted degradation routes of arbitrary PBDE congener. The routes of selected congeners were validated by the two independently published data sets and showed the high fitting degree. The model can be easily modified for any reactor system if the initial reaction rate constant of one congener is available for the given system.
Citace poskytuje Crossref.org
- 000
- 00000naa a2200000 a 4500
- 001
- bmc15031769
- 003
- CZ-PrNML
- 005
- 20151009113053.0
- 007
- ta
- 008
- 151005s2015 gw f 000 0|eng||
- 009
- AR
- 024 7_
- $a 10.1007/s11356-014-3741-7 $2 doi
- 035 __
- $a (PubMed)25345925
- 040 __
- $a ABA008 $b cze $d ABA008 $e AACR2
- 041 0_
- $a eng
- 044 __
- $a gw
- 100 1_
- $a Vesely, M $u Institute of Chemical Process Fundamentals, AS CR, v. v. i., Rozvojova 135, 165 02, Prague 6, Czech Republic.
- 245 10
- $a Model for photodegradation of polybrominated diphenyl ethers / $c M. Vesely, Z. Vajglova, P. Kotas, J. Kristal, R. Ponec, V. Jiricny,
- 520 9_
- $a Polybrominated diphenyl ethers (PBDE) were, and in some countries still are, used as flame retardants for plastic materials. When released from plastics, PDBE cause harm to the environment. This creates the incentive for further investigation of the PBDE degradation. This work focused on a formulation of a PBDE photodegradation model based on the PBDE properties obtained by the quantum chemical calculations. The proposed model predicted degradation routes of arbitrary PBDE congener. The routes of selected congeners were validated by the two independently published data sets and showed the high fitting degree. The model can be easily modified for any reactor system if the initial reaction rate constant of one congener is available for the given system.
- 650 _2
- $a počítačová simulace $7 D003198
- 650 _2
- $a retardanty hoření $x analýza $7 D005411
- 650 _2
- $a halogenované difenylethery $x chemie $7 D055768
- 650 12
- $a teoretické modely $7 D008962
- 650 _2
- $a molekulární struktura $7 D015394
- 650 12
- $a fotolýza $7 D010782
- 650 _2
- $a reprodukovatelnost výsledků $7 D015203
- 655 _2
- $a časopisecké články $7 D016428
- 655 _2
- $a práce podpořená grantem $7 D013485
- 700 1_
- $a Vajglova, Z
- 700 1_
- $a Kotas, P
- 700 1_
- $a Kristal, J
- 700 1_
- $a Ponec, R
- 700 1_
- $a Jiricny, V
- 773 0_
- $w MED00001558 $t Environmental science and pollution research international $x 1614-7499 $g Roč. 22, č. 7 (2015), s. 4949-63
- 856 41
- $u https://pubmed.ncbi.nlm.nih.gov/25345925 $y Pubmed
- 910 __
- $a ABA008 $b sig $c sign $y a $z 0
- 990 __
- $a 20151005 $b ABA008
- 991 __
- $a 20151009113240 $b ABA008
- 999 __
- $a ok $b bmc $g 1092645 $s 914895
- BAS __
- $a 3
- BAS __
- $a PreBMC
- BMC __
- $a 2015 $b 22 $c 7 $d 4949-63 $e 20141028 $i 1614-7499 $m Environmental science and pollution research international $n Environ. sci. pollut. res. int. $x MED00001558
- LZP __
- $a Pubmed-20151005
