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Chalcogen Bonding due to the Exo-Substitution of Icosahedral Dicarbaborane
J. Fanfrlík, D. Hnyk, P. Hobza,
Language English Country Switzerland
Document type Journal Article
Grant support
17-08045S
Grantová Agentura České Republiky
NLK
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- MeSH
- Boranes chemistry MeSH
- Chalcogens chemistry MeSH
- Crystallization MeSH
- Models, Molecular MeSH
- Static Electricity MeSH
- Thermodynamics MeSH
- Publication type
- Journal Article MeSH
Chalcogen atoms are a class of substituents capable of generating inner and outer derivatives of boron clusters. It is well known that chalcogenated boron clusters can form strong σ-hole interactions when a chalcogen atom is a part of an icosahedron. This paper studies σ-hole interactions of dicarbaboranes with two exopolyhedral chalcogen atoms bonded to carbon vertices. Specifically, a computational investigation has been carried out on the co-crystal of (1,2-C2B10H10)2Se4•toluene and a single crystal of (1,2-C2B10H10)2Te4.
References provided by Crossref.org
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- $a Chalcogen atoms are a class of substituents capable of generating inner and outer derivatives of boron clusters. It is well known that chalcogenated boron clusters can form strong σ-hole interactions when a chalcogen atom is a part of an icosahedron. This paper studies σ-hole interactions of dicarbaboranes with two exopolyhedral chalcogen atoms bonded to carbon vertices. Specifically, a computational investigation has been carried out on the co-crystal of (1,2-C2B10H10)2Se4•toluene and a single crystal of (1,2-C2B10H10)2Te4.
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