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The dynamics of band (peak) shape development in capillary zone electrophoresis in light of the linear theory of electromigration
M. Dvořák, P. Dubský, M. Dovhunová, B. Gaš,
Language English Country Germany
Document type Journal Article, Research Support, Non-U.S. Gov't, Review
Grant support
15-18424Y
Czech Science Foundation - International
18-11776S
Czech Science Foundation - International
GAUK 116217
Charles University Grant Agency - International
UNCE/SCI/014
Charles University Research Centre - International
- MeSH
- Models, Chemical * MeSH
- Electrophoresis, Capillary * MeSH
- Ions analysis chemistry isolation & purification MeSH
- Models, Statistical MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Review MeSH
The continuity equations that describe the movement of ions in liquid solutions under the influence of an external stationary electric field, as it is utilized in electrophoresis, were introduced a long time ago starting with Kohlrausch in 1897. From that time on, there have been many attempts to solve the equations and to discuss the results. In electrophoresis, special attention has always been devoted to the peak shapes obtained by the detector since the shapes have a tight connection with the phenomena taking place during electromigration and influence the efficiency and selectivity of the separation. Among these phenomena, the most important is electromigration dispersion. In this commented review paper, we compare various models of electromigration, try to find points that connect them, and discuss the range of their validity in light of the linear and nonlinear theory of electromigration.
References provided by Crossref.org
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- $a The continuity equations that describe the movement of ions in liquid solutions under the influence of an external stationary electric field, as it is utilized in electrophoresis, were introduced a long time ago starting with Kohlrausch in 1897. From that time on, there have been many attempts to solve the equations and to discuss the results. In electrophoresis, special attention has always been devoted to the peak shapes obtained by the detector since the shapes have a tight connection with the phenomena taking place during electromigration and influence the efficiency and selectivity of the separation. Among these phenomena, the most important is electromigration dispersion. In this commented review paper, we compare various models of electromigration, try to find points that connect them, and discuss the range of their validity in light of the linear and nonlinear theory of electromigration.
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