The title compound, [Na(C(12)H(8)N(2))(3)](C(3)H(2)N(3)S(3)), contains an Na(+) centre which is ionicly bonded to three 1,10-phenanthroline (phen) ligands and one trithiocyanurate(1-) (ttcH(2)) anion. In the crystal structure, the anions are linked via hydrogen bonds to form linear chains. The S and H atoms of the ttcH(2) anion participate in intermolecular N-H.S hydrogen bonding, with N.S distances of 3.298 (2) and 3.336 (2) A. The phen ligands are almost parallel, with dihedral angles of 3.92 (5), 11.75 (5) and 15.45 (5) degrees; moreover, they are nearly perpendicular to the ttcH(2) chains, with angles of 81.94 (7), 85.86 (7) and 85.96 (7) degrees.

Laboratory of Functional Genomics and Proteomics Faculty of Science Masaryk University Kotlárská 2 CZ 611 37 Brno Czech Republic

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