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2J(29Si-O-29Si) coupling constants in oligosiloxanes

. 2007 Aug ; 45 (8) : 685-7.

Status PubMed-not-MEDLINE Language English Country Great Britain, England Media print

Document type Journal Article

The absolute values of spin-spin couplings between (29)Si nuclei in siloxanes, (2)J((29)Si-O-(29)Si), were determined. The couplings are small and cover a narrow range of values (0-5 Hz). The coupling constants depend on the branching or on the number of electronegative substituents on the Si-O-Si moiety.

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