Bioinspired interactions studied by vibrational circular dichroism
Jazyk angličtina Země Spojené státy americké Médium print
Typ dokumentu časopisecké články, práce podpořená grantem, přehledy
PubMed
19937957
DOI
10.1002/chir.20803
Knihovny.cz E-zdroje
- MeSH
- chemické modely MeSH
- cirkulární dichroismus metody MeSH
- DNA chemie MeSH
- molekulární modely MeSH
- molekulární struktura MeSH
- oligonukleotidy chemie MeSH
- proteiny chemie MeSH
- spektrofotometrie infračervená metody MeSH
- stereoizomerie MeSH
- vibrace MeSH
- žlučové pigmenty chemie MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- přehledy MeSH
- Názvy látek
- DNA MeSH
- oligonukleotidy MeSH
- proteiny MeSH
- žlučové pigmenty MeSH
Vibrational circular dichroism (VCD) spectra are reliable indicators of the spatial structure of chiral molecules. The specific and characteristic feature of vibrational spectroscopy, and therefore also of VCD, where the energy of some vibrational modes is predominantly focused to a specific part of the molecule, enables monitoring both the structure of the molecule dissolved in different solvents and under different physicochemical conditions and molecular interactions. This minireview deals with recent contributions covering structural information on the bioinspired interactions obtained by means of VCD, especially in the following areas: interaction of DNA with biomolecules and biogenic metals, guanine tetramers and quadruplexes, biointeractions of bile pigments, and polypeptide and protein interactions with other biomolecules.
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