Flavin-cyclodextrin conjugates as catalysts of enantioselective sulfoxidations with hydrogen peroxide in aqueous media
Language English Country England, Great Britain Media print-electronic
Document type Journal Article, Research Support, Non-U.S. Gov't
PubMed
20835467
DOI
10.1039/c0cc02562c
Knihovny.cz E-resources
- MeSH
- beta-Cyclodextrins chemistry MeSH
- Flavins chemistry MeSH
- Catalysis MeSH
- Oxidation-Reduction MeSH
- Hydrogen Peroxide chemistry MeSH
- Stereoisomerism MeSH
- Sulfides chemistry MeSH
- Water chemistry MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Names of Substances
- beta-Cyclodextrins MeSH
- betadex MeSH Browser
- Flavins MeSH
- methylphenylsulfide MeSH Browser
- Hydrogen Peroxide MeSH
- Sulfides MeSH
- Water MeSH
β-Cyclodextrin-flavin conjugates are highly efficient catalysts for the sulfoxidation of methyl phenyl sulfides with hydrogen peroxide in neat aqueous media operating at loadings down to 0.2 mol% and allowing for enantioselectivities up to 80% ee.
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