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Calix[4]arenes with intramolecularly bridged meta positions prepared via Pd-catalysed double C-H activation

. 2013 Apr 07 ; 49 (27) : 2798-800.

Status PubMed-not-MEDLINE Language English Country England, Great Britain Media print

Document type Journal Article

The introduction of a 2-pyridylsulfoxide moiety into the upper rim of calix[4]arenes enabled the synthesis of unprecedented derivatives with intramolecularly bridged meta positions of two neighbouring aromatic subunits. Palladium-catalysed double C-H activation thus represents a straightforward way to a completely novel type of calixarenes.

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