Use of residual dipolar couplings in conformational analysis of meta-disubstituted calix[4]arenes
Status PubMed-not-MEDLINE Jazyk angličtina Země Anglie, Velká Británie Médium print
Typ dokumentu časopisecké články
PubMed
24820209
DOI
10.1039/c4cc02274b
Knihovny.cz E-zdroje
- Publikační typ
- časopisecké články MeSH
Dimercuration of tetrapropoxy calix[4]arene followed by a reaction with isoamyl nitrite afforded dinitroso regioisomers with unique substitution patterns. The unusual conformational behaviour of these inherently chiral systems was revealed by the combination of dynamic NMR and residual dipolar coupling (RDC) techniques.
Citace poskytuje Crossref.org
Enantiodiscrimination of Inherently Chiral Thiacalixarenes by Residual Dipolar Couplings