Test-photostability of pulsed laser deposited amorphous thin films from Ge-As-Te system
Status PubMed-not-MEDLINE Jazyk angličtina Země Velká Británie, Anglie Médium electronic
Typ dokumentu časopisecké články, práce podpořená grantem
PubMed
25797340
PubMed Central
PMC4369751
DOI
10.1038/srep09310
PII: srep09310
Knihovny.cz E-zdroje
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
Amorphous thin films from Ge-As-Te system were prepared by pulsed laser deposition to study their intrinsic photostability, morphology, chemical composition, structure and optical properties. Photostability of fabricated layers was studied by spectroscopic ellipsometry within as-deposited as well as relaxed (annealed) layers. For irradiation, laser sources operating at three wavelengths in band gap region of the studied materials were employed. The results show that lowest values of photorefraction accompanied with lowest changes of band gap values were exhibited by Ge20As20Te60 thin films, which are therefore considered as the layers with highest photostability in relaxed state. The structure of the films is discussed based on Raman scattering spectroscopy data.
Zobrazit více v PubMed
Shimakawa K., Kolobov A. & Elliott S. R. Photoinduced effects and metastability in amorphous semiconductors and insulators. Adv. Phys. 44, 475–588 (1995).
Chauvet M. et al. Kerr spatial solitons in chalcogenide waveguides. Opt. Lett. 34, 1804–1806 (2009). PubMed
Nemec P., Nazabal V. & Frumar M. Photoinduced phenomena in amorphous As4Se3 pulsed laser deposited thin films studied by spectroscopic ellipsometry. J. Appl. Phys. 106, 023509 (2009).
Sleeckx E., Tichy L., Nagels P. & Callaerts R. Thermally and photo-induced irreversible changes in the optical properties of amorphous GexSe100-x films. J. Non-Cryst. Solids 200, 723–727 (1996).
Vateva E. Giant photo- and thermo-induced effects in chalcogenides. J. Optoelectron. Adv. Mater. 9, 3108–3114 (2007).
Yang G. et al. A photo-stable chalcogenide glass. Opt. Express 16, 10565–10571 (2008). PubMed
Nemec P. et al. Photo-stability of pulsed laser deposited GexAsySe100-x-y amorphous thin films. Opt. Express 18, 22944–22957 (2010). PubMed
Su X., Wang R., Luther-Davies B. & Wang L. The dependence of photosensitivity on composition for thin films of GexAsySe1-x-y chalcogenide glasses. Appl. Phys. A-Mater. Sci. Process. 113, 575–581 (2013).
Khan P. et al. Coexistence of fast photodarkening and slow photobleaching in Ge19As21Se60 thin films. Opt. Express 20, 12416–12421 (2012). PubMed
Khan P., Jain H. & Adarsh K. V. Role of Ge: As ratio in controlling the light-induced response of a-GexAs35-xSe65 thin films. Sci. Rep. 4, 4029 (2014). PubMed PMC
Khan P., Saxena T., Jain H. & Adarsh K. V. Nanosecond light induced, thermally tunable transient dual absorption bands in a-Ge5As30Se65 thin film. Sci. Rep. 4, 6573 (2014). PubMed PMC
Eggleton B. J., Luther-Davies B. & Richardson K. Chalcogenide photonics. Nature Photonics 5, 141–148 (2011).
Bureau B. et al. Tellurium based glasses: A ruthless glass to crystal competition. Solid State Sci. 10, 427–433 (2008).
Yang Z. Y. & Lucas P. Tellurium-based far-infrared transmitting glasses. J. Am. Ceram. Soc. 92, 2920–2923 (2009).
Hawlová P., Verger F., Nazabal V., Boidin R. & Němec P. Accurate determination of optical functions of Ge–As–Te glasses via spectroscopic ellipsometry. J. Am. Ceram. Soc. 97, 3044–3047 (2014).
Mohamed S. H., Wakkad M. M., Ahmed. & Diab A. M. Structural and optical properties of Ge-As-Te thin films. The European Physical Journal Applied Physics 34, 165–171 (2006).
Pinto R. Threshold and memory switching in thin films of the chalcogenide systems Ge-As-Te and Ge-As-Se. Thin Solid Films 7, 391–404 (1971).
Nemec P., Takats V., Csik A. & Kokenyesi S. GeSe/GeS nanomultilayers prepared by pulsed laser deposition. J. Non-Cryst. Solids 354, 5421–5424 (2008).
Nemec P. et al. Pulsed laser deposited amorphous chalcogenide and alumino-silicate thin films and their multilayered structures for photonic applications. Thin Solid Films 539, 226–232 (2013).
Hawlova P., Olivier M., Verger F., Nazabal V. & Nemec P. Photosensitivity of pulsed laser deposited Ge20As20Se60 and Ge10As30Se60 amorphous thin films. Mater. Res. Bull. 48, 3860–3864 (2013).
Krebs H. & Fischer P. Electrical conductivity of melts and their ability to form glasses in the system Ge + As + Te. Discussions of the Faraday Society 50, 35–44 (1970).
Calvez L., Yang Z. Y. & Lucas P. Light-induced matrix softening of Ge-As-Se network glasses. Phys. Rev. Lett. 101, 177402 (2008). PubMed
Tanaka K. Photo-Induced Metastability in Amorphous Semiconductors [Kolobov A. V. (ed.)] [69–90] (Wiley-WCH, Weinheim, 2003).
Wuttig M. & Raoux S. The science and technology of phase change materials. Z. Anorg. Allg. Chem. 638, 2455–2465 (2012).
Andrikopoulos K. S. et al. Raman scattering study of the a-GeTe structure and possible mechanism for the amorphous to crystal transition. J. Phys.: Condens. Matter 18, 965–979 (2006).
Sen S., Gjersing E. L. & Aitken B. G. Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure. J. Non-Cryst. Solids 356, 2083–2088 (2010).
Brodsky M. H., Smith J. E., Yacoby Y. & Gambino R. J. Raman spectrum of amorphous tellurium. Phys. Status Solidi B-Basic Res. 52, 609–614 (1972).
Pine A. S. & Dresselhaus G. Raman spectra and lattice dynamics of tellurium. Phys. Rev. B 4, 356–371 (1971).
Steigmeier E. F. & Harbeke G. Soft phonon mode and ferroelectricity in GeTe. Solid State Commun. 8, 1275–1279 (1970).
Voleska I. et al. Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study. Phys. Rev. B 86, 094108 (2012).
Kolobov A. V. & Tanaka K. Handbook of Advanced Electronic and Photonic Materials and Devices Vol. 5 [Nalwa H. S. (ed.)] [47–85] (Academic Press, London, 2001).
Shimakawa K., Yoshida N., Ganjoo A., Kuzukawa Y. & Singh J. A Model for the Photostructural Changes in Amorphous Chalcogenides. Philos. Mag. Lett. 77, 153–158 (1998).
Tanaka K. Sub-gap excitation effects in As2S3 glass. J. Non-Cryst. Solids 266, 889–893 (2000).
Yang C. Y., Paesler M. A. & Sayers D. E. Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulfide films. Phys. Rev. B 36, 9160–9167 (1987). PubMed
Chen G., Jain H., Vlcek M. & Ganjoo A. Photoinduced volume change in arsenic chalcogenides by band-gap light. Phys. Rev. B 74, 174203 (2006).
Cody G. D. Semiconductors and Semimetals Vol. 21, Part B [Pankove J. I. (ed.)] [11–82] (Academic Press, London, 1984).
Tailoring of Multisource Deposition Conditions towards Required Chemical Composition of Thin Films