Surface Inclusion of Unidirectional Molecular Motors in Hexagonal Tris(o-phenylene)cyclotriphosphazene
Status PubMed-not-MEDLINE Jazyk angličtina Země Spojené státy americké Médium print-electronic
Typ dokumentu časopisecké články, Research Support, U.S. Gov't, Non-P.H.S., práce podpořená grantem
PubMed
28654753
DOI
10.1021/jacs.7b05404
Knihovny.cz E-zdroje
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Research Support, U.S. Gov't, Non-P.H.S. MeSH
A new unidirectional light-driven molecular motor suitable for host-guest surface inclusion complexes with tris(o-phenylene)cyclotriphosphazene (TPP) was synthesized. The motor molecules formed regular two-dimensional trigonal arrays covering the large facets of disc-shaped TPP nanocrystals. Photochemical and thermal isomerization studies demonstrated that the light-driven rotation of the anchored motors is similar to that observed in solution and is not compromised neither by either the surface confinement or the density of surface coverage (50 vs 100%).
Department of Chemistry and Biochemistry University of Colorado Boulder Colorado 80309 United States
Department of Physics University of Colorado Boulder Colorado 80309 United States
Institute of Organic Chemistry and Biochemistry AS CR Flemingovo nám 2 166 10 Praha 6 Czech Republic
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