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Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

Bakardjiev, Mario
Author Bakardjiev, Mario Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-ŘeŽ 1001, Czech Republic
Tok, Oleg L
Author Tok, Oleg L Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-ŘeŽ 1001, Czech Republic
RůŽička, Aleš
Author RůŽička, Aleš Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic
RůŽičková, Zdeňka
Author RůŽičková, Zdeňka Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic
Holub, Josef
Author Holub, Josef Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-ŘeŽ 1001, Czech Republic
Hnyk, Drahomír
Author Hnyk, Drahomír ORCID Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-ŘeŽ 1001, Czech Republic
Špalt, Zbyněk
Author Špalt, Zbyněk Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-ŘeŽ 1001, Czech Republic
Fanfrlík, Jindřich
Author Fanfrlík, Jindřich ORCID Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic
Štíbr, Bohumil
Author Štíbr, Bohumil ORCID Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-ŘeŽ 1001, Czech Republic

Dalton transactions (Cambridge, England. 2018 Aug 14 ; 47 (32) : 11070-11076.

Dalton Trans
ISSN 1477-9234 | 1477-9226
Source

Status PubMed-not-MEDLINE Language English Country Great Britain, England Media print

Document type Journal Article

Persistent link https://www.medvik.cz/link/pmid30033463

PubMed 30033463
DOI 10.1039/c8dt02586j
Knihovny.cz E-resources

Publication type
Journal Article MeSH

Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C2B8 scaffolding inside the egg-shaped hepta - decamethyl sheath, which imparts unusually high air and solvolytic stability to all of these compounds.

Department of General and Inorganic Chemistry Faculty of Chemical Technology University of Pardubice Studentská 573 532 10 Pardubice Czech Republic

Institute of Inorganic Chemistry Academy of Sciences of the Czech Republic Husinec ŘeŽ 1001 Czech Republic

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences Flemingovo nám 2 166 10 Prague 6 Czech Republic

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Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

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