In this present investigation, aluminium (Al3+) fabricated 2-aminobenzene-1,4-dicarboxylic acid (ABDC) namely Al@ABDC metal organic frameworks (MOFs) was developed for defluoridation studies. The unique advantages of developed MOFs possess high selectivity, high porosity and enhanced surface area but the developed powder form of Al@ABDC MOFs has several limitations in field applications like slow filtration and column blockage. To prevail over these troubles, biopolymer namely chitosan (CS) supported Al@ABDC MOFs namely Al@ABDC-CS beads were developed for effective fluoride adsorption from water. The synthesized Al@ABDC-CS beads were employed for the retention of fluoride in batch level. The defluoridation capacities (DCs) of Al@ABDC MOFs and Al@ABDC-CS beads were found to be 4880 and 4900 mgF- kg-1 respectively. The influencing parameters of adsorption method namely agitation time, adsorbent dosage, initial fluoride concentration, pH, co-existing anions and temperature were exploit to get utmost defluoridation capacity (DC) of Al@ABDC-CS beads. The experimental data of Al@ABDC-CS beads have been evaluated utilizing Langmuir, Fruendlich and Dubinin-Radushkevich (D-R) isotherms. The defluoridation nature of Al@ABDC-CS beads was determined by the thermodynamic parameters. The order of reaction of Al@ABDC-CS beads was studied using various kinetic models. The regeneration and field water studies of Al@ABDC-CS beads were also carried out to check their reusability and suitability at field conditions.

Department of Chemistry Anna University University College of Engineering Dindigul Dindigul 624 622 Tamilnadu India

Department of Chemistry College of Science Kind Saud University P O Box 2455 Riyadh 11451 Saudi Arabia

Faculty of Civil Engineering Department of Landscape and Water Conservation Czech Technical University Prague Thakurova 7 166 29 Prague 6 Czech Republic

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