Porous architectures characterized by parallel channels arranged in honeycomb or rectangular patterns are identified in two polymorphic crystals of a zwitterionic 4-(aryliodonio)-benzenesulfonate. The channels are filled with disordered water molecules which can be reversibly removed on heating. Consistent with the remarkable strength and directionality of the halogen bonds (XBs) driving the crystal packing formation, the porous structure is stable and fully preserved on almost quantitative removal and readsorption of water. The porous systems described here are the first reported cases of one-component 3D organic frameworks whose assembly is driven by XB only (XOFs). These systems are a proof of concept for the ability of zwitterionic aryliodonium tectons in affording robust one-component 3D XOFs. The high directionality and strength of the XBs formed by these zwitterions and the geometrical constraints resulting from the tendency of their hypervalent iodine atoms to act as bidentate XB donors might be key factors in determining this ability.

Australian Institute for Bioengineering and Nanotechnology The University of Queensland Brisbane QLD 4072 Australia

Departament de Química Universitat de les Illes Balears Crta de Valldemossa Km 7 5 07122 Palma de Mallorca Spain

Department of Chemistry and Biochemistry University of Minnesota Duluth MN 55812 USA

Department of Solid State Engineering Institute of Chemical Technology Prague 16628 Czech Republic

Institute of Chemistry Saint Petersburg State University Saint Petersburg 199034 Russian Federation

JST ERATO Yamauchi Materials Space Tectonics Project National Institute for Materials Science 1 1 Namiki Tsukuba Ibaraki 305 0044 Japan

NFMLab Department of Chemistry Materials and Chemical Engineering Giulio Natta ; Politecnico di Milano via Mancinelli 7 1 20131 Milano Italy

Research School of Chemistry and Applied Biomedical Sciences Tomsk Polytechnic University Tomsk 634034 Russian Federation

School of Chemistry Cardiff University Park Place Cardiff UK

Serveis Científico Tècnics Universitat de les Illes Balears Crta de Valldemossa Km 7 5 07122 Palma de Mallorca Spain

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