Graphene Nanobeacons with High-Affinity Pockets for Combined, Selective, and Effective Decontamination and Reagentless Detection of Heavy Metals
Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články, práce podpořená grantem
Grantová podpora
No 683024
European Research Council - International
PubMed
35775954
DOI
10.1002/smll.202201003
Knihovny.cz E-zdroje
- Klíčová slova
- carboxylation, heavy metals, nitrogen-doped graphene acid, paper-based sensors, sensing, sorption,
- MeSH
- adsorpce MeSH
- dekontaminace MeSH
- grafit * MeSH
- kadmium MeSH
- olovo MeSH
- těžké kovy * MeSH
- voda MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- grafit * MeSH
- kadmium MeSH
- olovo MeSH
- těžké kovy * MeSH
- voda MeSH
Access to clean water for drinking, sanitation, and irrigation is a major sustainable development goal of the United Nations. Thus, technologies for cleaning water and quality-monitoring must become widely accessible and of low-cost, while being effective, selective, sustainable, and eco-friendly. To meet this challenge, hetero-bifunctional nanographene fluorescent beacons with high-affinity pockets for heavy metals are developed, offering top-rated and selective adsorption for cadmium and lead, reaching 870 and 450 mg g-1 , respectively. The heterobifunctional and multidentate pockets also operate as selective gates for fluorescence signal regulation with sub-nanomolar sensitivity (0.1 and 0.2 nm for Pb2+ and Cd2+ , respectively), due to binding affinities as low as those of antigen-antibody interactions. Importantly, the acid-proof nanographenes can be fully regenerated and reused. Their broad visible-light absorption offers an additional mode for water-quality monitoring based on ultra-low cost and user-friendly reagentless paper detection with the naked-eye at a limit of detection of 1 and 10 ppb for Pb2+ and Cd2+ ions, respectively. This work shows that photoactive nanomaterials, densely-functionalized with strong, yet selective ligands for targeted contaminants, can successfully combine features such as excellent adsorption, reusability, and sensing capabilities, in a way to extend the material's applicability, its life-cycle, and value-for-money.
Department of Materials Science and Engineering University of Ioannina Ioannina 45110 Greece
ICREA Institució Catalana de Recerca i Estudis Avançats Pg Lluís Companys 23 Barcelona 08010 Spain
Physics Department University of Ioannina Ioannina 45110 Greece
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