Benchmark Dynamics of Dipolar Molecular Rotors in Fluorinated Metal-Organic Frameworks
Status PubMed-not-MEDLINE Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články
Grantová podpora
Dipartimenti di Eccellenza
PRIN NEMO-20173L7W8K
Ministero dell'Istruzione, dell'Università e della Ricerca
PRIN SHERPA-2020EZ8EPB
Ministero dell'Istruzione, dell'Università e della Ricerca
ID22 beamline (Project: HC-4781)
European Synchrotron Radiation Facility
Enhancing Photosynthesis
Regione Lombardia
Czech Academy of Sciences (RVO: 61388963)
Ústav organické chemie a biochemie Akademie věd České republiky
(grant number: 20-13745S)
Ústav organické chemie a biochemie Akademie věd České republiky
PubMed
36469012
DOI
10.1002/anie.202215893
Knihovny.cz E-zdroje
- Klíčová slova
- Crystal Engineering, Fluorine, Metal Organic Frameworks, Molecular Dynamics, Molecular Rotor,
- Publikační typ
- časopisecké články MeSH
Fluorinated Metal-Organic Frameworks (MOFs), comprising a wheel-shaped ligand with geminal rotating fluorine atoms, produced benchmark mobility of correlated dipolar rotors at 2 K, with practically null activation energy (Ea =17 cal mol-1 ). 1 H T1 NMR revealed multiple relaxation phenomena due to the exchange among correlated dipole-rotor configurations. Synchrotron radiation X-ray diffraction at 4 K, Density Functional Theory, Molecular Dynamics and phonon calculations showed the fluid landscape and pointed out a cascade mechanism converting dipole configurations into each other. Gas accessibility, shown by hyperpolarized-Xe NMR, allowed for chemical stimuli intervention: CO2 triggered dipole reorientation, reducing their collective dynamics and stimulating a dipole configuration change in the crystal. Dynamic materials under limited thermal noise and high responsiveness enable the fabrication of molecular machines with low energy dissipation and controllable dynamics.
Department of Materials Science University of Milano Bicocca Via R Cozzi 55 20125 Milan Italy
Department of Physics University of Pavia Via Bassi 6 27100 Pavia Italy
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