Converter gas is a large scale waste product that is usually burned to carbon dioxide and contributes to the world emission of greenhouse gases. Herein we demonstrate that instead of burning the converter gas can be used as a reducing agent in organic reactions to produce valuable pharmaceuticals and agrochemicals. In particular, amide-based selected drug molecules have been synthesized by a reaction of aromatic nitro compounds and carboxylic acids in the presence of converter gas. In addition, we showed that this gas can also be conveniently utilized to carryout classical reductive amination reaction.

A N Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Vavilova St 28 Moscow 119991 Russian Federation

Department of Applied Homogeneous Catalysis Leibniz Institut für Katalyse e 5 Albert Einstein Straße 29A Rostock 18059 Germany

Faculty of Chemistry of the National Research University Higher School of Economics Miasnitskaya Str 20 Moscow 101000 Russian Federation

Nanotechnology Centre Centre of Energy and Environmental Technologies VŠB Technical University of Ostrava Ostrava Poruba Czech Republic

Plekhanov Russian University of Economics Stremyanny per 36 Moscow 117997 Russian Federation

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