In this report, a 2D MOF nanosheet derived Pd single-atom catalyst, denoted as Pd-MOF, was fabricated and examined for visible light photocatalytic hydrogen evolution reaction (HER). This Pd-MOF can provide a remarkable photocatalytic activity (a H2 production rate of 21.3 mmol/gh in the visible range), which outperforms recently reported Pt-MOFs (with a H2 production rate of 6.6 mmol/gh) with a similar noble metal loading. Notably, this high efficiency of Pd-MOF is not due to different chemical environment of the metal center, nor by changes in the spectral light absorption. The higher performance of the Pd-MOF in comparison to the analogue Pt-MOF is attributed to the longer lifetime of the photogenerated electron-hole pairs and higher charge transfer efficiency.

Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials Physical Chemistry I Friedrich Alexander Universität Erlangen Nürnberg Egerlandstraße 3 91058 Erlangen Germany

Department of Materials Science WW4 LKO Friedrich Alexander University of Erlangen Nuremberg Martensstrasse 7 91058 Erlangen Germany

Regional Centre of Advanced Technologies and Materials Czech Advanced Technology and Research Institute Palacký University Olomouc Šlechtitelů 241 27 78371 Olomouc Czech Republic

Regional Centre of Advanced Technologies and Materials Šlechtitelů 27 78371 Olomouc Czech Republic

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Single Atom Cocatalysts in Photocatalysis