Methamphetamine Removal from Aquatic Environments by Magnetic Microrobots with Cyclodextrin Chiral Recognition Elements
Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články, práce podpořená grantem
Grantová podpora
No. CZ.02.01.01/00/22_008/0004587
ERDF/ESF project TECHSCALE
CZ.10.03.01/00/22_003/0000048
European Union under the REFRESH - Research Excellence For REgion Sustainability and High-tech Industries project number
NU21-08-00407
Ministry of Health of the Czech Republic
PubMed
38239086
DOI
10.1002/smll.202306943
Knihovny.cz E-zdroje
- Klíčová slova
- illicit drugs, iron oxides, magnetic actuation, water remediation,
- MeSH
- chemické látky znečišťující vodu * chemie izolace a purifikace MeSH
- čištění vody metody MeSH
- cyklodextriny * chemie MeSH
- magnetismus MeSH
- methamfetamin * chemie MeSH
- robotika MeSH
- železité sloučeniny chemie MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- chemické látky znečišťující vodu * MeSH
- cyklodextriny * MeSH
- ferric oxide MeSH Prohlížeč
- methamfetamin * MeSH
- železité sloučeniny MeSH
The growing consumption of drugs of abuse together with the inefficiency of the current wastewater treatment plants toward their presence has resulted in an emergent class of pollutants. Thus, the development of alternative approaches to remediate this environmental threat is urgently needed. Microrobots, combining autonomous motion with great tunability for the development of specific tasks, have turned into promising candidates to take on the challenge. Here, hybrid urchin-like hematite (α-Fe2O3) microparticles carrying magnetite (Fe3O4) nanoparticles and surface functionalization with organic β-cyclodextrin (CD) molecules are prepared with the aim of on-the-fly encapsulation of illicit drugs into the linked CD cavities of moving microrobots. The resulting mag-CD microrobots are tested against methamphetamine (MA), proving their ability for the removal of this psychoactive substance. A dramatically enhanced capture of MA from water with active magnetically powered microrobots when compared with static passive CD-modified particles is demonstrated. This work shows the advantages of enhanced mass transfer provided by the externally controlled magnetic navigation in microrobots that together with the versatility of their design is an efficient strategy to clean polluted waters.
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