BODIPY phototether enables oligonucleotide cyclization and subsequent deprotection by tissue-transparent red light
Status PubMed-not-MEDLINE Jazyk angličtina Země Anglie, Velká Británie Médium electronic
Typ dokumentu časopisecké články
PubMed
38563214
DOI
10.1039/d4cc00272e
Knihovny.cz E-zdroje
- Publikační typ
- časopisecké články MeSH
meso-methyl-BODIPY photocages release a leaving group upon visible light irradiation but often lack thermal stability. In turn, our thermally-stable, red-shifted BODIPY phototether allows oligonucleotide cyclization, preventing complementary strand hybridization. Hybridization resumes upon red-NIR irradiation, disconnecting the phototether by oxidative cleavage, which is easily monitored by a blue shift in fluorescence.
Goethe Universität Frankfurt Max von Laue Strasse 7 Frankfurt am Main 60438 Germany
Institute of Organic Chemistry and Biochemistry Flemingovo náměstí 542 Prague 160 00 Czech Republic
Citace poskytuje Crossref.org
