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Blast furnace slags as sorbents of phosphate from water solutions
Kostura B, Kulveitová H, Lesko J
Jazyk angličtina Země Velká Británie
Typ dokumentu srovnávací studie
NLK
ScienceDirect (archiv)
od 1993-01-01 do 2009-12-31
- MeSH
- adsorpce MeSH
- chemické látky znečišťující vodu izolace a purifikace MeSH
- čištění vody metody MeSH
- finanční podpora výzkumu jako téma MeSH
- fosfor chemie izolace a purifikace MeSH
- kinetika MeSH
- koncentrace vodíkových iontů MeSH
- kovy analýza chemie MeSH
- průmyslový odpad analýza MeSH
- spalování odpadů MeSH
- zachování přírodních zdrojů MeSH
- Publikační typ
- srovnávací studie MeSH
The paper is focused on the sorption of phosphorus from aqueous solutions by crystalline and amorphous blast furnace slags. Slag sorption kinetics were measured, adsorption tests were carried out and the effect of acidification on the sorption properties of slags was studied. The kinetic measurements confirmed that the sorption of phosphorus on crystalline as well as amorphous slags can be described by a model involving pseudo-second-order reactions. For all slag types, phosphorus sorption follows the Langmuir adsorption isotherm. The acid neutralizing capacities of crystalline and amorphous slags were determined. In the case of the crystalline slags, buffering intervals were found to exist during which the slag minerals dissolve in the sequence bredigite-gehlenite-diaspor. There is a high correlation (R2=0.9989) between ANC3.8 and the saturation capacities of crystalline and amorphous slags.
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- $a Chemistry Department, VSB-Technical University Ostrava, 17. listopadu, 15, 708 33 Ostrava-Poruba, Czech Republic. bruno.kostura@vsb.cz
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- $a The paper is focused on the sorption of phosphorus from aqueous solutions by crystalline and amorphous blast furnace slags. Slag sorption kinetics were measured, adsorption tests were carried out and the effect of acidification on the sorption properties of slags was studied. The kinetic measurements confirmed that the sorption of phosphorus on crystalline as well as amorphous slags can be described by a model involving pseudo-second-order reactions. For all slag types, phosphorus sorption follows the Langmuir adsorption isotherm. The acid neutralizing capacities of crystalline and amorphous slags were determined. In the case of the crystalline slags, buffering intervals were found to exist during which the slag minerals dissolve in the sequence bredigite-gehlenite-diaspor. There is a high correlation (R2=0.9989) between ANC3.8 and the saturation capacities of crystalline and amorphous slags.
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