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Twenty years of development of dual and multi-selector models in capillary electrophoresis: a review
L. Müllerová, P. Dubský, B. Gaš,
Jazyk angličtina Země Německo
Typ dokumentu časopisecké články, práce podpořená grantem, přehledy
PubMed
24946108
DOI
10.1002/elps.201400149
Knihovny.cz E-zdroje
- MeSH
- chromatografie micelární elektrokinetická kapilární MeSH
- cyklodextriny MeSH
- elektroforéza kapilární * přístrojové vybavení metody MeSH
- stereoizomerie MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- přehledy MeSH
It has been 20 years since Lurie et al. first published their model of electromigration of an analyte under simultaneous interaction with two cyclodextrins as chiral selectors. Since then, the theory of (enantio)separation in dual and complex mixtures of (chiral) selectors is well understood. In spite of this, a trial-and-error approach still prevails in analytical practice. Such a situation is likely caused by the fact that the entire theory is spread over numerous papers and the relations between various models are not always clear. The present review condenses the theory for the first time. Available mathematical models and feasible practical approaches are summarized and their advantages and limitations discussed.
Citace poskytuje Crossref.org
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- $a It has been 20 years since Lurie et al. first published their model of electromigration of an analyte under simultaneous interaction with two cyclodextrins as chiral selectors. Since then, the theory of (enantio)separation in dual and complex mixtures of (chiral) selectors is well understood. In spite of this, a trial-and-error approach still prevails in analytical practice. Such a situation is likely caused by the fact that the entire theory is spread over numerous papers and the relations between various models are not always clear. The present review condenses the theory for the first time. Available mathematical models and feasible practical approaches are summarized and their advantages and limitations discussed.
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