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Organochlorine pesticides and polychlorinated biphenyls along an east-to-west gradient in subtropical North Atlantic surface water
G. Lammel, A. Spitzy, O. Audy, S. Beckmann, GP. Codling, L. Kretzschmann, P. Kukučka, I. Stemmler,
Jazyk angličtina Země Německo
Typ dokumentu časopisecké články
NLK
ProQuest Central
od 1997-03-01 do 2017-12-31
Health & Medicine (ProQuest)
od 1997-03-01 do 2017-12-31
Public Health Database (ProQuest)
od 1997-03-01 do 2017-12-31
- MeSH
- chlorované uhlovodíky analýza MeSH
- monitorování životního prostředí MeSH
- mořská voda analýza MeSH
- pesticidy analýza MeSH
- polychlorované bifenyly analýza MeSH
- Publikační typ
- časopisecké články MeSH
- Geografické názvy
- Atlantský oceán MeSH
Despite the fact that most persistent toxic substances have hardly been primarily emitted for several decades, their concentrations are only slowly decreasing in the global oceans. Surface seawater samples were collected along a 38°-24° N/28°-67° W transect in the subtropical North Atlantic Ocean. While the concentration levels of hexachlorobenzene (2.1-6.1 pg L(-1)), dichlorodiphenyltrichloroethane (DDT, up to 2.1 pg L(-1)) and polychlorinated biphenyls (PCB, 10.8-24.9 pg L(-1)) were in the same range as observed earlier in the North Atlantic, hexachlorocyclohexane (HCH, 90-627 pg L(-1)) was found elevated, partly also relative to previous measurements in the same sea region. Hereby, the ratio α-HCH/γ-HCH was very low, 0.09-0.13. Chlordane and endosulfan were found in the range <3.0-11.1 and <5.8-8.8 pg L(-1) respectively. DDT metabolites, endrin and related pesticides were found below quantification limits. Spatial pollution patterns in surface seawaters seem to be determined by atmospheric and oceanic transport patterns, rather than by mixing and air-sea equilibrium. The comparison with global multicompartment chemistry-transport model predictions of surface seawater levels indicate underestimated degradation of PCBs and overestimated emissions of endosulfan.
Max Planck Institute for Meteorology Hamburg Germany
Research Centre for Toxic Compounds in the Environment Masaryk University Brno Czech Republic
Citace poskytuje Crossref.org
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- $a Lammel, Gerhard $u Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany. g.lammel@mpic.de. Research Centre for Toxic Compounds in the Environment, Masaryk University, Brno, Czech Republic. g.lammel@mpic.de.
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- $a Organochlorine pesticides and polychlorinated biphenyls along an east-to-west gradient in subtropical North Atlantic surface water / $c G. Lammel, A. Spitzy, O. Audy, S. Beckmann, GP. Codling, L. Kretzschmann, P. Kukučka, I. Stemmler,
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- $a Despite the fact that most persistent toxic substances have hardly been primarily emitted for several decades, their concentrations are only slowly decreasing in the global oceans. Surface seawater samples were collected along a 38°-24° N/28°-67° W transect in the subtropical North Atlantic Ocean. While the concentration levels of hexachlorobenzene (2.1-6.1 pg L(-1)), dichlorodiphenyltrichloroethane (DDT, up to 2.1 pg L(-1)) and polychlorinated biphenyls (PCB, 10.8-24.9 pg L(-1)) were in the same range as observed earlier in the North Atlantic, hexachlorocyclohexane (HCH, 90-627 pg L(-1)) was found elevated, partly also relative to previous measurements in the same sea region. Hereby, the ratio α-HCH/γ-HCH was very low, 0.09-0.13. Chlordane and endosulfan were found in the range <3.0-11.1 and <5.8-8.8 pg L(-1) respectively. DDT metabolites, endrin and related pesticides were found below quantification limits. Spatial pollution patterns in surface seawaters seem to be determined by atmospheric and oceanic transport patterns, rather than by mixing and air-sea equilibrium. The comparison with global multicompartment chemistry-transport model predictions of surface seawater levels indicate underestimated degradation of PCBs and overestimated emissions of endosulfan.
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