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Generalized model of the linear theory of electromigration and its application to electrokinetic chromatography: Theory and software PeakMaster 6-Next Generation

M. Malý, M. Dovhunová, M. Dvořák, GS. Gerlero, PA. Kler, V. Hruška, P. Dubský,

. 2019 ; 40 (5) : 683-692. [pub] 20190104

Jazyk angličtina Země Německo

Typ dokumentu časopisecké články, práce podpořená grantem

Perzistentní odkaz   https://www.medvik.cz/link/bmc19045093

Grantová podpora
15-18424Y Czech Science Foundation - International
UNCE/SCI/014 Charles University Research Centre - International
GA UK 726716 Charles University Grant Agency - International
GA UK 116217 Charles University Grant Agency - International
PICT-2016-0640 National Scientific and Technical Research Council (Agencia Nacional de Promoción Científica y Tecnológica - ANPCyT) - International
PID ASUT-NFE0004475 National Technological University (Universidad Tecnológica Nacional - UTN) - International

The linear theory of electromigration, including the first-order nonlinear approximation, is generalized to systems with any equilibria fast enough to be considered instantaneous in comparison with the timescale of peak movement. For example, this theory is practically applied in the electrokinetic chromatography (EKC) mode of the CZE. The model enables the calculation of positions and shapes of analyte and system peaks without restricting the number of selectors, the complexation stoichiometry, or simultaneous acid-base equilibria. The latest version of our PeakMaster software, PeakMaster 6-Next Generation, implements the theory in a user-friendly way. It is a free and open-source software that performs all calculations and shows the properties of the background electrolyte and the expected electropherogram within a few seconds. In this paper, we mathematically derive the model, discuss its applicability to EKC systems, and introduce the PeakMaster 6 software.

Citace poskytuje Crossref.org

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