Macrolactone glycosides of three lichen acids from Acarospora gobiensis, a lichen of Central Asia
Language English Country Great Britain, England Media print
Document type Journal Article
PubMed
11738423
DOI
10.1016/s0031-9422(01)00388-0
PII: S0031-9422(01)00388-0
Knihovny.cz E-resources
- MeSH
- Glycolipids MeSH
- Glycosides chemistry isolation & purification MeSH
- Lichens chemistry MeSH
- Publication type
- Journal Article MeSH
- Geographicals
- Russia MeSH
- Names of Substances
- Glycolipids MeSH
- Glycosides MeSH
- gobienine A MeSH Browser
- gobienine B MeSH Browser
- gobienine C MeSH Browser
The compounds isolated from the extract of Central Asian lichen (Acarospora gobiensis H. Magn.) comprised three new glycosides having 18-hydroxy-dihydroalloprotolichesterinic, 18-hydroxy-neodihydroprotolichesterinic and 18-hydroxy-dihydroprotolichesterinic acids as aglycones and a di- or trisaccharide moiety linked at C-18 and at the carboxylic group. These compounds, called gobienines A-C, were found to be di- or trisacharides forming a macrolactone with the aglycone. The structures were elucidated by using extensive spectroscopic analysis (1D and 2D NMR, MS, IR and ORD) and chemical and enzymatic methods.
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Compounds isolated at the Institute of Microbiology in 1989-2001 and future trends