Macrolactone glycosides of three lichen acids from Acarospora gobiensis, a lichen of Central Asia

. 2001 Dec ; 58 (8) : 1281-7.

Jazyk angličtina Země Anglie, Velká Británie Médium print

Typ dokumentu časopisecké články

Perzistentní odkaz   https://www.medvik.cz/link/pmid11738423
Odkazy

PubMed 11738423
DOI 10.1016/s0031-9422(01)00388-0
PII: S0031-9422(01)00388-0
Knihovny.cz E-zdroje

The compounds isolated from the extract of Central Asian lichen (Acarospora gobiensis H. Magn.) comprised three new glycosides having 18-hydroxy-dihydroalloprotolichesterinic, 18-hydroxy-neodihydroprotolichesterinic and 18-hydroxy-dihydroprotolichesterinic acids as aglycones and a di- or trisaccharide moiety linked at C-18 and at the carboxylic group. These compounds, called gobienines A-C, were found to be di- or trisacharides forming a macrolactone with the aglycone. The structures were elucidated by using extensive spectroscopic analysis (1D and 2D NMR, MS, IR and ORD) and chemical and enzymatic methods.

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