A spectroelectrochemical approach to the electrodeposition of bismuth film electrodes and their use in stripping analysis
Jazyk angličtina Země Nizozemsko Médium print-electronic
Typ dokumentu časopisecké články, práce podpořená grantem
PubMed
18215645
DOI
10.1016/j.aca.2007.12.023
PII: S0003-2670(07)02034-X
Knihovny.cz E-zdroje
- MeSH
- bismut chemie MeSH
- časové faktory MeSH
- elektrody MeSH
- kadmium chemie MeSH
- pokovování galvanické * MeSH
- spektrofotometrie metody MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- bismut MeSH
- kadmium MeSH
UV-vis reflection spectroelectrochemistry has proven to be a very useful multiresponse technique to evaluate the quality of bismuth films obtained by electrochemical deposition on glassy carbon electrodes (GCEs). Bismuth films have recently emerged as a promising and environmental friendly alternative to mercury electrodes for stripping analysis. Spectroelectrochemical measurements, carried out in a flow cell, allowed us to follow in situ the electrodeposition and stripping of bismuth and cadmium. Electrochemical and spectroscopic responses individually have led to successfully quantify the amount of cadmium in test solutions.
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