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Improved thermooxidation and sedimentation stability of covalently-coated carbonyl iron particles with cholesteryl groups and their influence on magnetorheology

. 2013 Apr 15 ; 396 () : 146-51. [epub] 20130131

Status PubMed-not-MEDLINE Language English Country United States Media print-electronic

Document type Journal Article

Links

PubMed 23433972
DOI 10.1016/j.jcis.2013.01.027
PII: S0021-9797(13)00065-9
Knihovny.cz E-resources

Sedimentation of particles in magnetorheological suspensions represents a crucial problem that concerns their efficient long-term application in practice. Prepared carbonyl iron (CI) microparticles coated with a low density substance, cholesteryl chloroformate, via a two-step reaction and immersed in silicone oil, exhibit three positive aspects: (1) the CI particle modification increased the compatibility between the particles and the silicone oil resulting in improved long-term stability (reduction in sedimentation); (2) the coating provided the particles with enhanced thermal stability in the oxygen atmosphere; and (3) rheological measurements proved a promising magnetorheological performance at different particle weight fractions.

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