• This record comes from PubMed

meta-Bridged calix[4]arenes: a straightforward synthesis via organomercurial chemistry

. 2013 Aug 04 ; 49 (60) : 6749-51.

Status PubMed-not-MEDLINE Language English Country England, Great Britain Media print

Document type Journal Article

Persistent link   https://www.medvik.cz/link/pmid23778584

The regioselective mercuration of tetraalkylated calix[4]arenes with Hg(OCOCF3)2 leads to the formation of meta-substituted products which enabled Pd-catalysed intramolecular bridging within the calixarene skeleton. Bridged derivatives represent a completely novel substitution pattern in calixarene chemistry with extremely distorted cavities and possible applications in supramolecular chemistry.

References provided by Crossref.org

Find record

Citation metrics

Archiving options