Synthesis of quaternary α-perfluoroalkyl lactams via electrophilic perfluoroalkylation
Language English Country England, Great Britain Media print
Document type Journal Article, Research Support, Non-U.S. Gov't
PubMed
26893124
DOI
10.1039/c6cc00700g
Knihovny.cz E-resources
- MeSH
- Ethylenes chemistry MeSH
- Hydrocarbons, Fluorinated chemical synthesis chemistry MeSH
- Indicators and Reagents chemistry MeSH
- Iodine chemistry MeSH
- Catalysis MeSH
- Ketones chemistry MeSH
- Lactams chemical synthesis chemistry MeSH
- Molecular Structure MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Names of Substances
- Ethylenes MeSH
- Hydrocarbons, Fluorinated MeSH
- Indicators and Reagents MeSH
- Iodine MeSH
- ketene MeSH Browser
- Ketones MeSH
- Lactams MeSH
Efficient protocols enabling the rapid installation of trifluoromethyl, as well as further functionalized fluoroalkyl groups by an electrophilic perfluoroalkylation of lactam-derived ketene silyl amides (KSAs) using hypervalent iodine reagents 1 and 2 have been developed.
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