Deeply cooled and temperature controlled microjets: Liquid ammonia solutions released into vacuum for analysis by photoelectron spectroscopy
Status PubMed-not-MEDLINE Language English Country United States Media print
Document type Journal Article
PubMed
32357686
DOI
10.1063/1.5141359
Knihovny.cz E-resources
- Publication type
- Journal Article MeSH
A versatile, temperature controlled apparatus is presented, which generates deeply cooled liquid microjets of condensed gases, expelling them via a small aperture into vacuum for use in photoelectron spectroscopy (PES). The functionality of the design is demonstrated by temperature- and concentration-dependent PES measurements of liquid ammonia and solutions of KI and NH4I in liquid ammonia. The experimental setup is not limited to the usage of liquid ammonia solutions solely.
Department of Chemistry University of Southern California Los Angeles California 90089 0482 USA
Fritz Haber Institut der Max Planck Gesellschaft Molekülphysik Faradayweg 4 6 14195 Berlin Germany
References provided by Crossref.org
Stability and Reactivity of Aromatic Radical Anions in Solution with Relevance to Birch Reduction
Observation of intermolecular Coulombic decay and shake-up satellites in liquid ammonia