Redox-Active Metaphosphate-Like Terminals Enable High-Capacity MXene Anodes for Ultrafast Na-Ion Storage
Status PubMed-not-MEDLINE Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články
Grantová podpora
881603
European Union's Horizon 2020
100478697
Sächsisches Staatsministerium für Wissenschaft und Kunst
417590517
German Research Foundation
52072241
National Natural Science Foundation of China
51772187
National Natural Science Foundation of China
19-26910X
Czech Science Foundation
China Scholarship Council
PubMed
35148441
DOI
10.1002/adma.202108682
Knihovny.cz E-zdroje
- Klíčová slova
- MXenes, hybrid-ion capacitors, redox-active terminals, sodium-ion storage,
- Publikační typ
- časopisecké články MeSH
2D transition metal carbides and/or nitrides, so-called MXenes, are noted as ideal fast-charging cation-intercalation electrode materials, which nevertheless suffer from limited specific capacities. Herein, it is reported that constructing redox-active phosphorus-oxygen terminals can be an attractive strategy for Nb4 C3 MXenes to remarkably boost their specific capacities for ultrafast Na+ storage. As revealed, redox-active terminals with a stoichiometric formula of PO2 - display a metaphosphate-like configuration with each P atom sustaining three PO bonds and one PO dangling bond. Compared with conventional O-terminals, metaphosphate-like terminals empower Nb4 C3 (denoted PO2 -Nb4 C3 ) with considerably enriched carrier density (fourfold), improved conductivity (12.3-fold at 300 K), additional redox-active sites, boosted Nb redox depth, nondeclined Na+ -diffusion capability, and buffered internal stress during Na+ intercalation/de-intercalation. Consequently, compared with O-terminated Nb4 C3 , PO2 -Nb4 C3 exhibits a doubled Na+ -storage capacity (221.0 mAh g-1 ), well-retained fast-charging capability (4.9 min at 80% capacity retention), significantly promoted cycle life (nondegraded capacity over 2000 cycles), and justified feasibility for assembling energy-power-balanced Na-ion capacitors. This study unveils that the molecular-level design of MXene terminals provides opportunities for developing simultaneously high-capacity and fast-charging electrodes, alleviating the energy-power tradeoff typical for energy-storage devices.
Faculty of Chemistry University of Warsaw ul Żwirki i Wigury 101 Warsaw 02 089 Poland
Leibniz Institute for Solid State and Materials Research Dresden e 5 01069 Dresden Germany
Max Planck Institute for Polymer Research Ackermannweg 10 D 55128 Mainz Germany
Max Planck Institute of Microstructure Physics Weinberg 2 06120 Halle Germany
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