We present the fabrication and use of a film of a carborane-thiol-protected tetranuclear copper cluster with characteristic orange luminescence using ambient electrospray deposition (ESD). Charged microdroplets of the clusters produced by an electrospray tip deposit the clusters at an air-water interface to form a film. Different microscopic and spectroscopic techniques characterized the porous surface structure of the film. Visible and rapid quenching of the emission of the film upon exposure to 2-nitrotoluene (2-NT) vapours under ambient conditions was observed. Density functional theory (DFT) calculations established the favourable binding sites of 2-NT with the cluster. Desorption of 2-NT upon heating recovered the original luminescence, demonstrating the reusability of the sensor. Stable emission upon exposure to different organic solvents and its quenching upon exposure to 2,4-dinitrotoluene and picric acid showed selectivity of the film to nitroaromatic species.

Department of Chemistry DST Unit of Nanoscience Indian Institute of Technology Madras Chennai 600036 India

Department of Chemistry Indian Institute of Technology Indore Indore 453552 India

Department of Synthesis Institute of Inorganic Chemistry The Czech Academy of Science 1001 Husinec Rez 25068 Czech Republic

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