Enantioselective Adsorption on Magnetic Surfaces
Status PubMed-not-MEDLINE Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články
Grantová podpora
277146847
Deutsche Forschungsgemeinschaft
PubMed
38153192
DOI
10.1002/adma.202308666
Knihovny.cz E-zdroje
- Klíčová slova
- CISS, chirality, enantiospecific adsorption, magnetic surfaces, van der Waals interactions,
- Publikační typ
- časopisecké články MeSH
From the beginning of molecular theory, the interplay of chirality and magnetism has intrigued scientists. There is still the question if enantiospecific adsorption of chiral molecules occurs on magnetic surfaces. Enantiomer discrimination was conjectured to arise from chirality-induced spin separation within the molecules and exchange interaction with the substrate's magnetization. Here, it is shown that single helical aromatic hydrocarbons undergo enantioselective adsorption on ferromagnetic cobalt surfaces. Spin and chirality sensitive scanning tunneling microscopy reveals that molecules of opposite handedness prefer adsorption onto cobalt islands with opposite out-of-plane magnetization. As mobility ceases in the final chemisorbed state, it is concluded that enantioselection must occur in a physisorbed transient precursor state. State-of-the-art spin-resolved ab initio simulations support this scenario by refuting enantio-dependent chemisorption energies. These findings demonstrate that van der Waals interaction should also include spin-fluctuations which are crucial for molecular magnetochiral processes.
Fakultät für Physik Universität Duisburg Essen 47057 Duisburg Germany
Institut für Chemie Universität Zürich 8057 Zürich Switzerland
Nanosurf Laboratory Institute of Physics The Czech Academy of Sciences 16200 Prague Czech Republic
Peter Grünberg Institute Electronic Properties Forschungszentrum Jülich 52425 Jülich Germany
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